2 ∶ 1 Ba/Ti(iv) Heterobimetallic complex based on two calix[6]arenes

Antonella J. Petrella; Nicholas K. Roberts; Donald C. Craig; Colin L. Raston; Robert N. Lamb

doi:10.1039/b302346j

2 ∶ 1 Ba/Ti(iv) Heterobimetallic complex based on two calix[6]arenes

Antonella J. Petrella, Nicholas K. Roberts, Donald C. Craig, Colin L. Raston, Robert N. Lamb

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Reaction of p-Bu^t-calix[6]arene with barium metal in methanol then [Ti(OPrⁱ)₄] affords a heterobimetallic complex with a central Ti(iv) attached to two calix[6]arenes in the 1,3-alternate conformation, each with an endo-barium sharing common phenolate groups with the titanium centre.

Original language	English
Pages (from-to)	2288-2289
Number of pages	2
Journal	Chemical Communications
Volume	3
Issue number	18
DOIs	https://doi.org/10.1039/b302346j
Publication status	Published - 12 Aug 2003
Externally published	Yes

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abstract = "Reaction of p-But-calix[6]arene with barium metal in methanol then [Ti(OPri)4] affords a heterobimetallic complex with a central Ti(iv) attached to two calix[6]arenes in the 1,3-alternate conformation, each with an endo-barium sharing common phenolate groups with the titanium centre.",

author = "Petrella, {Antonella J.} and Roberts, {Nicholas K.} and Craig, {Donald C.} and Raston, {Colin L.} and Lamb, {Robert N.}",

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AU - Petrella, Antonella J.

AU - Roberts, Nicholas K.

AU - Craig, Donald C.

AU - Raston, Colin L.

AU - Lamb, Robert N.

PY - 2003/8/12

Y1 - 2003/8/12

N2 - Reaction of p-But-calix[6]arene with barium metal in methanol then [Ti(OPri)4] affords a heterobimetallic complex with a central Ti(iv) attached to two calix[6]arenes in the 1,3-alternate conformation, each with an endo-barium sharing common phenolate groups with the titanium centre.

AB - Reaction of p-But-calix[6]arene with barium metal in methanol then [Ti(OPri)4] affords a heterobimetallic complex with a central Ti(iv) attached to two calix[6]arenes in the 1,3-alternate conformation, each with an endo-barium sharing common phenolate groups with the titanium centre.

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JF - Chemical Communications

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2 ∶ 1 Ba/Ti(iv) Heterobimetallic complex based on two calix[6]arenes

Abstract

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