A 3-D diamondoid MOF catalyst based on in situ generated [Cu(L)2] N-heterocyclic carbene (NHC) linkers: hydroboration of CO2

Alexandre Burgun; Rachel Crees; Marcus Cole; Christian Doonan; Christopher Sumby

doi:10.1039/c4cc04761c

A 3-D diamondoid MOF catalyst based on in situ generated [Cu(L)2] N-heterocyclic carbene (NHC) linkers: hydroboration of CO2

Alexandre Burgun, Rachel Crees, Marcus Cole, Christian Doonan, Christopher Sumby

College of Science and Engineering

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

A new MOF, [Zn ₄O(Cu(L) ₂) ₂] (1), with a 4-fold interpenetrated 3D diamondoid structure was synthesised from in situ generated [Cu(L) ₂] NHC linkers. MOF 1 possesses tetrahedral Zn ₄O nodes, which are unusually coordinated by four pairs of carboxylates from four [Cu(L) ₂] linkers, and 14 å 1-D pore channels lined with [Cu(L) ₂] moieties that catalyse the hydroboration of CO ₂.

Original language	English
Pages (from-to)	11760-11763
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	79
DOIs	https://doi.org/10.1039/c4cc04761c
Publication status	Published - 9 Sept 2014

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title = "A 3-D diamondoid MOF catalyst based on in situ generated [Cu(L)2] N-heterocyclic carbene (NHC) linkers: hydroboration of CO2",

abstract = "A new MOF, [Zn 4O(Cu(L) 2) 2] (1), with a 4-fold interpenetrated 3D diamondoid structure was synthesised from in situ generated [Cu(L) 2] NHC linkers. MOF 1 possesses tetrahedral Zn 4O nodes, which are unusually coordinated by four pairs of carboxylates from four [Cu(L) 2] linkers, and 14 {\aa} 1-D pore channels lined with [Cu(L) 2] moieties that catalyse the hydroboration of CO 2.",

author = "Alexandre Burgun and Rachel Crees and Marcus Cole and Christian Doonan and Christopher Sumby",

year = "2014",

month = sep,

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doi = "10.1039/c4cc04761c",

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journal = "Chemical Communications",

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T1 - A 3-D diamondoid MOF catalyst based on in situ generated [Cu(L)2] N-heterocyclic carbene (NHC) linkers: hydroboration of CO2

AU - Burgun, Alexandre

AU - Crees, Rachel

AU - Cole, Marcus

AU - Doonan, Christian

AU - Sumby, Christopher

PY - 2014/9/9

Y1 - 2014/9/9

N2 - A new MOF, [Zn 4O(Cu(L) 2) 2] (1), with a 4-fold interpenetrated 3D diamondoid structure was synthesised from in situ generated [Cu(L) 2] NHC linkers. MOF 1 possesses tetrahedral Zn 4O nodes, which are unusually coordinated by four pairs of carboxylates from four [Cu(L) 2] linkers, and 14 å 1-D pore channels lined with [Cu(L) 2] moieties that catalyse the hydroboration of CO 2.

AB - A new MOF, [Zn 4O(Cu(L) 2) 2] (1), with a 4-fold interpenetrated 3D diamondoid structure was synthesised from in situ generated [Cu(L) 2] NHC linkers. MOF 1 possesses tetrahedral Zn 4O nodes, which are unusually coordinated by four pairs of carboxylates from four [Cu(L) 2] linkers, and 14 å 1-D pore channels lined with [Cu(L) 2] moieties that catalyse the hydroboration of CO 2.

UR - http://www.scopus.com/inward/record.url?scp=84923336007&partnerID=8YFLogxK

U2 - 10.1039/c4cc04761c

DO - 10.1039/c4cc04761c

M3 - Article

SN - 1359-7345

VL - 50

SP - 11760

EP - 11763

JO - Chemical Communications

JF - Chemical Communications

IS - 79

ER -

A 3-D diamondoid MOF catalyst based on in situ generated [Cu(L)2] N-heterocyclic carbene (NHC) linkers: hydroboration of CO2

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