Abstract
Reaction of barium metal with 2-pyridylphenylmethane in liquid ammonia, thf and diglyme at -50°C then ca. 70°C yields the metallated bent 'open metallocene' with the metal centre bound in an η5 manner to the ipso-C, adjacent C-centres and nearest N, C centres, a tridentate diglyme and a thf molecule [Ba-C, N 2.983(6)-3.303(6) Å, Ba-O 2.766(4)-2.855(4) Å determined at -100°C].
| Original language | English |
|---|---|
| Pages (from-to) | 1795-1796 |
| Number of pages | 2 |
| Journal | Chemical Communications |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - 1 Jan 1996 |
| Externally published | Yes |
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Gardiner, M. G., Raston, C. L., & Viebrock, H. (1996). A bent 'barocene' based on metallated 2-pyridylphenylmethane: [Ba{η5-PhCH(C5H4N-2)} 2{MeO(CH2)2O(CH2) 2OMe}(thf)]. Chemical Communications, (15), 1795-1796. https://doi.org/10.1039/CC9960001795