### Abstract

We report absolute differential cross sections (DCSs) for elastic electron scattering from OCS (carbonyl sulphide) and CS_{2} (carbon disulphide) in the impact energy range of 1.2-200 eV and for scattering angles from 10° to 150°. Above 10 eV, the angular distributions are found to agree quite well with our present calculations using two semi-phenomenological theoretical approaches. One employs the independent-atom model with the screening-corrected additivity rule (IAM-SCAR), while the other uses the continuum-multiple- scattering method in conjunction with a parameter-free exchange-polarization approximation. Since OCS is a polar molecule, further dipole-induced rotational excitation cross sections have been calculated in the framework of the first Born approximation and incoherently added to the IAM-SCAR results. In comparison with the calculated DCS for the S atom, atomic-like behavior for the angular distributions in both the OCS and CS_{2} scattering systems is observed. Integrated elastic cross sections are obtained by extrapolating the experimental measurements, with the aid of the theoretical calculations, for those scattering angles below 10° and above 150°. These values are then compared with the available total cross sections.

Original language | English |
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Article number | 054302 |

Pages (from-to) | 054302-054302 |

Number of pages | 12 |

Journal | Journal of Chemical Physics |

Volume | 138 |

Issue number | 5 |

DOIs | |

Publication status | Published - 7 Feb 2013 |

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## Cite this

*Journal of Chemical Physics*,

*138*(5), 054302-054302. [054302]. https://doi.org/10.1063/1.4788666