A covalent deprotection strategy for assembling supramolecular coordination polymers from metal-organic cages

Matthew L. Schneider; Oliver M. Linder-Patton; Witold M. Bloch

doi:10.1039/d0cc05349j

A covalent deprotection strategy for assembling supramolecular coordination polymers from metal-organic cages

Matthew L. Schneider, Oliver M. Linder-Patton, Witold M. Bloch

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

A Cu4L4 metal-organic cage (MOC) composed of amine-protected ligands forms supramolecular coordination polymers (SCPs) upon covalent post-assembly deprotection. The amorphous SCPs form by virtue of aniline-copper coordination and possess a tunable porosity based on the rate of deprotection.

Original language	English
Pages (from-to)	12969-12972
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	85
DOIs	https://doi.org/10.1039/d0cc05349j
Publication status	Published - 4 Nov 2020
Externally published	Yes

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title = "A covalent deprotection strategy for assembling supramolecular coordination polymers from metal-organic cages",

abstract = "A Cu4L4 metal-organic cage (MOC) composed of amine-protected ligands forms supramolecular coordination polymers (SCPs) upon covalent post-assembly deprotection. The amorphous SCPs form by virtue of aniline-copper coordination and possess a tunable porosity based on the rate of deprotection. ",

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AU - Bloch, Witold M.

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AB - A Cu4L4 metal-organic cage (MOC) composed of amine-protected ligands forms supramolecular coordination polymers (SCPs) upon covalent post-assembly deprotection. The amorphous SCPs form by virtue of aniline-copper coordination and possess a tunable porosity based on the rate of deprotection.

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UR - http://purl.org/au-research/grants/ARC/DE190100327

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M3 - Article

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JO - Chemical Communications

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A covalent deprotection strategy for assembling supramolecular coordination polymers from metal-organic cages

Abstract

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