A gem-aluminium(III)/antimony(III) C centre incorporated in a bimetallic six-membered heterocycle

Philip C. Andrews, Colin L. Raston, Brian W. Skelton, Allan H. White

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Reaction of AlMe3 with the implied stibene intermediate (-Sb=C<) formed in the reaction of [(2-pyr)(SiMe3)2CLi· tmeda] with SbCl3 affords the carboalumination product containing a gem-Al/Sb C centre as part of a six-membered heterocycle, [(2-pyr)(SiMe3)2C-Sb(Me)-(2-pyr)(SiMe 3)C-Al(Me)2] 1, structurally authenticated as the (RS,SR) diastereoisomer.

Original languageEnglish
Pages (from-to)1183-1184
Number of pages2
JournalChemical Communications
Issue number13
DOIs
Publication statusPublished - 1 Jan 1997
Externally publishedYes

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