Abstract
Reaction of AlMe3 with the implied stibene intermediate (-Sb=C<) formed in the reaction of [(2-pyr)(SiMe3)2CLi· tmeda] with SbCl3 affords the carboalumination product containing a gem-Al/Sb C centre as part of a six-membered heterocycle, [(2-pyr)(SiMe3)2C-Sb(Me)-(2-pyr)(SiMe 3)C-Al(Me)2] 1, structurally authenticated as the (RS,SR) diastereoisomer.
Original language | English |
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Pages (from-to) | 1183-1184 |
Number of pages | 2 |
Journal | Chemical Communications |
Issue number | 13 |
DOIs | |
Publication status | Published - 1 Jan 1997 |
Externally published | Yes |