A gem-aluminium(III)/antimony(III) C centre incorporated in a bimetallic six-membered heterocycle

Philip C. Andrews; Colin L. Raston; Brian W. Skelton; Allan H. White

doi:10.1039/a700959c

A gem-aluminium(III)/antimony(III) C centre incorporated in a bimetallic six-membered heterocycle

Philip C. Andrews, Colin L. Raston, Brian W. Skelton, Allan H. White

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

Reaction of AlMe₃ with the implied stibene intermediate (-Sb=C<) formed in the reaction of [(2-pyr)(SiMe₃)₂CLi· tmeda] with SbCl₃ affords the carboalumination product containing a gem-Al/Sb C centre as part of a six-membered heterocycle, [(2-pyr)(SiMe₃)₂C-Sb(Me)-(2-pyr)(SiMe ₃)C-Al(Me)₂] 1, structurally authenticated as the (RS,SR) diastereoisomer.

Original language	English
Pages (from-to)	1183-1184
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/a700959c
Publication status	Published - 1 Jan 1997
Externally published	Yes

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title = "A gem-aluminium(III)/antimony(III) C centre incorporated in a bimetallic six-membered heterocycle",

abstract = "Reaction of AlMe3 with the implied stibene intermediate (-Sb=C<) formed in the reaction of [(2-pyr)(SiMe3)2CLi· tmeda] with SbCl3 affords the carboalumination product containing a gem-Al/Sb C centre as part of a six-membered heterocycle, [(2-pyr)(SiMe3)2C-Sb(Me)-(2-pyr)(SiMe 3)C-Al(Me)2] 1, structurally authenticated as the (RS,SR) diastereoisomer.",

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AU - Andrews, Philip C.

AU - Raston, Colin L.

AU - Skelton, Brian W.

AU - White, Allan H.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - Reaction of AlMe3 with the implied stibene intermediate (-Sb=C<) formed in the reaction of [(2-pyr)(SiMe3)2CLi· tmeda] with SbCl3 affords the carboalumination product containing a gem-Al/Sb C centre as part of a six-membered heterocycle, [(2-pyr)(SiMe3)2C-Sb(Me)-(2-pyr)(SiMe 3)C-Al(Me)2] 1, structurally authenticated as the (RS,SR) diastereoisomer.

AB - Reaction of AlMe3 with the implied stibene intermediate (-Sb=C<) formed in the reaction of [(2-pyr)(SiMe3)2CLi· tmeda] with SbCl3 affords the carboalumination product containing a gem-Al/Sb C centre as part of a six-membered heterocycle, [(2-pyr)(SiMe3)2C-Sb(Me)-(2-pyr)(SiMe 3)C-Al(Me)2] 1, structurally authenticated as the (RS,SR) diastereoisomer.

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U2 - 10.1039/a700959c

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EP - 1184

JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

A gem-aluminium(III)/antimony(III) C centre incorporated in a bimetallic six-membered heterocycle

Abstract

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