A heterobimetallic K2Ti2 complex incorporating two calix[5]arenes: A diverse array of metal-ligand interplay

Antonella J. Petrella, Nicholas K. Roberts, Donald C. Craig, Colin L. Raston, Robert N. Lamb

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Reaction of p-tBu-calix[5]arene with potassium metal in a mixture of methanol and THF followed by [Ti(acac)2(OPri)2] affords an unsymmetrical dimeric 1:1 K/Ti complex built up from a central Ti-O-Ti core with each titanium(IV) centre octahedrally coordinated, bearing an acac and a calix[5]arene encapsulating a potassium ion.

Original languageEnglish
Pages (from-to)1728-1729
Number of pages2
JournalChemical Communications
Volume3
Issue number14
DOIs
Publication statusPublished - 18 Jun 2003
Externally publishedYes

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