A maximum entropy model for branching ratios in multiple infrared photon dissociation

W. D. Lawrance; J. Silverstein; Fu Min Zhang; Qing Shi Zhu; J. S. Francisco; J. I. Steinfeld

doi:10.1021/j150614a001

A maximum entropy model for branching ratios in multiple infrared photon dissociation

W. D. Lawrance, J. Silverstein, Fu Min Zhang, Qing Shi Zhu, J. S. Francisco, J. I. Steinfeld

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A statistical model, similar to that suggested by Silberstein and Levine for multiphoton ionization, has been applied to the calculation of product branching ratios in the multiple infrared photon dissociation of chloro-cyclobutane. The maximum-entropy and RRKM models reproduce the experimental data equally well, but diverge from each other near the dissociation threshold.

Original language	English
Pages (from-to)	1961-1963
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	85
Issue number	14
DOIs	https://doi.org/10.1021/j150614a001
Publication status	Published - 9 Jul 1981
Externally published	Yes

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title = "A maximum entropy model for branching ratios in multiple infrared photon dissociation",

abstract = "A statistical model, similar to that suggested by Silberstein and Levine for multiphoton ionization, has been applied to the calculation of product branching ratios in the multiple infrared photon dissociation of chloro-cyclobutane. The maximum-entropy and RRKM models reproduce the experimental data equally well, but diverge from each other near the dissociation threshold.",

author = "Lawrance, {W. D.} and J. Silverstein and Zhang, {Fu Min} and Zhu, {Qing Shi} and Francisco, {J. S.} and Steinfeld, {J. I.}",

year = "1981",

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doi = "10.1021/j150614a001",

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journal = "Journal of Physical Chemistry B",

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T1 - A maximum entropy model for branching ratios in multiple infrared photon dissociation

AU - Lawrance, W. D.

AU - Silverstein, J.

AU - Zhang, Fu Min

AU - Zhu, Qing Shi

AU - Francisco, J. S.

AU - Steinfeld, J. I.

PY - 1981/7/9

Y1 - 1981/7/9

N2 - A statistical model, similar to that suggested by Silberstein and Levine for multiphoton ionization, has been applied to the calculation of product branching ratios in the multiple infrared photon dissociation of chloro-cyclobutane. The maximum-entropy and RRKM models reproduce the experimental data equally well, but diverge from each other near the dissociation threshold.

AB - A statistical model, similar to that suggested by Silberstein and Levine for multiphoton ionization, has been applied to the calculation of product branching ratios in the multiple infrared photon dissociation of chloro-cyclobutane. The maximum-entropy and RRKM models reproduce the experimental data equally well, but diverge from each other near the dissociation threshold.

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U2 - 10.1021/j150614a001

DO - 10.1021/j150614a001

M3 - Article

AN - SCOPUS:33845555996

VL - 85

SP - 1961

EP - 1963

JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

SN - 1520-6106

IS - 14

ER -

A maximum entropy model for branching ratios in multiple infrared photon dissociation

Abstract

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