A re-investigation of the reaction of [RuCl2(CO) 3]2 with C5H5(Me3Si) X-ray structure determination of [Ru(Co) 3(η-C5H5)][fac-RuCl3(CO) 3]

Christopher S. Griffith; George A. Koutsantonis; Colin L. Raston; John P. Selegue; Brian W. Skelton; Allan H. White

doi:10.1016/0022-328X(96)06196-7

A re-investigation of the reaction of [RuCl₂(CO) ₃]₂ with C₅H₅(Me₃Si) X-ray structure determination of [Ru(Co) ₃(η-C₅H₅)][fac-RuCl₃(CO) ₃]

Christopher S. Griffith, George A. Koutsantonis, Colin L. Raston, John P. Selegue, Brian W. Skelton, Allan H. White

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The reaction of [RuCl₂(CO)₃]₂ with C₅H₅(SiMe₃) has been re-investigated. In our hands, in refluxing tetrahydrofuran, the reaction gives consistently [Ru(CO)₃(η-C₅H₅)] [fac-RuCl₃(CO)₃], 1, and [RuCl(CO)₂(η-C₅H₅)], 2, in 68% and 12% yield respectively. The reaction of CO with commercially available hydrated OsCl₃ gives [OsCl₂(CO)₃]₂ in 44% yield. The crystal structure of [Ru(CO)₃(η-C₅H₅)] [fac-RuCl₃(CO)₃] is reported; superlattice symmetry is observed.

Original language	English
Pages (from-to)	197-202
Number of pages	6
Journal	JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume	518
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(96)06196-7
Publication status	Published - 12 Jul 1996
Externally published	Yes

Keywords

Carbonyl
Cyclopentadienyl
Ruthenium anion
Ruthenium cation
Silicon
Starting material
Superlattice symmetry

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@article{61f9f2d111cc4813894392e3df5c974e,

title = "A re-investigation of the reaction of [RuCl2(CO) 3]2 with C5H5(Me3Si) X-ray structure determination of [Ru(Co) 3(η-C5H5)][fac-RuCl3(CO) 3]",

abstract = "The reaction of [RuCl2(CO)3]2 with C5H5(SiMe3) has been re-investigated. In our hands, in refluxing tetrahydrofuran, the reaction gives consistently [Ru(CO)3(η-C5H5)] [fac-RuCl3(CO)3], 1, and [RuCl(CO)2(η-C5H5)], 2, in 68% and 12% yield respectively. The reaction of CO with commercially available hydrated OsCl3 gives [OsCl2(CO)3]2 in 44% yield. The crystal structure of [Ru(CO)3(η-C5H5)] [fac-RuCl3(CO)3] is reported; superlattice symmetry is observed.",

keywords = "Carbonyl, Cyclopentadienyl, Ruthenium anion, Ruthenium cation, Silicon, Starting material, Superlattice symmetry",

author = "Griffith, {Christopher S.} and Koutsantonis, {George A.} and Raston, {Colin L.} and Selegue, {John P.} and Skelton, {Brian W.} and White, {Allan H.}",

year = "1996",

month = jul,

day = "12",

doi = "10.1016/0022-328X(96)06196-7",

language = "English",

volume = "518",

pages = "197--202",

journal = "JOURNAL OF ORGANOMETALLIC CHEMISTRY",

issn = "0022-328X",

number = "1-2",

}

A re-investigation of the reaction of [RuCl₂(CO) ₃]₂ with C₅H₅(Me₃Si) X-ray structure determination of [Ru(Co) ₃(η-C₅H₅)][fac-RuCl₃(CO) ₃]. / Griffith, Christopher S.; Koutsantonis, George A.; Raston, Colin L.; Selegue, John P.; Skelton, Brian W.; White, Allan H.

In: JOURNAL OF ORGANOMETALLIC CHEMISTRY, Vol. 518, No. 1-2, 12.07.1996, p. 197-202.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - A re-investigation of the reaction of [RuCl2(CO) 3]2 with C5H5(Me3Si) X-ray structure determination of [Ru(Co) 3(η-C5H5)][fac-RuCl3(CO) 3]

AU - Griffith, Christopher S.

AU - Koutsantonis, George A.

AU - Raston, Colin L.

AU - Selegue, John P.

AU - Skelton, Brian W.

AU - White, Allan H.

PY - 1996/7/12

Y1 - 1996/7/12

N2 - The reaction of [RuCl2(CO)3]2 with C5H5(SiMe3) has been re-investigated. In our hands, in refluxing tetrahydrofuran, the reaction gives consistently [Ru(CO)3(η-C5H5)] [fac-RuCl3(CO)3], 1, and [RuCl(CO)2(η-C5H5)], 2, in 68% and 12% yield respectively. The reaction of CO with commercially available hydrated OsCl3 gives [OsCl2(CO)3]2 in 44% yield. The crystal structure of [Ru(CO)3(η-C5H5)] [fac-RuCl3(CO)3] is reported; superlattice symmetry is observed.

AB - The reaction of [RuCl2(CO)3]2 with C5H5(SiMe3) has been re-investigated. In our hands, in refluxing tetrahydrofuran, the reaction gives consistently [Ru(CO)3(η-C5H5)] [fac-RuCl3(CO)3], 1, and [RuCl(CO)2(η-C5H5)], 2, in 68% and 12% yield respectively. The reaction of CO with commercially available hydrated OsCl3 gives [OsCl2(CO)3]2 in 44% yield. The crystal structure of [Ru(CO)3(η-C5H5)] [fac-RuCl3(CO)3] is reported; superlattice symmetry is observed.

KW - Carbonyl

KW - Cyclopentadienyl

KW - Ruthenium anion

KW - Ruthenium cation

KW - Silicon

KW - Starting material

KW - Superlattice symmetry

UR - http://www.scopus.com/inward/record.url?scp=0030581079&partnerID=8YFLogxK

U2 - 10.1016/0022-328X(96)06196-7

DO - 10.1016/0022-328X(96)06196-7

M3 - Article

AN - SCOPUS:0030581079

VL - 518

SP - 197

EP - 202

JO - JOURNAL OF ORGANOMETALLIC CHEMISTRY

JF - JOURNAL OF ORGANOMETALLIC CHEMISTRY

SN - 0022-328X

IS - 1-2