A redetermination of the crystal structure of ‘Thorium(IV) tetrakis(trifluoroacetylacetonate)’: Stereochemistry of the system [M(bidentate ligand)4(unidentate ligand)]

Trevor W. Hambley, David L. Kepert, Colin L. Raston, Allan H. White

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The structure of ‘[Th(CF3COCHCOCH3)4]’ has been redetermined from diffractometer data and shown to be [Th(CF3COCHCOCH3)4(H2O)]. The stereochemistry is in agreement with that determined for the [M(bidentate ligand)4(unidentate ligand)]x± system by a calculation based on a repulsion model.

Original languageEnglish
Pages (from-to)2635-2640
Number of pages6
JournalAustralian Journal of Chemistry
Volume31
Issue number12
DOIs
Publication statusPublished - 1978
Externally publishedYes

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