Alkylaluminum Cations: Synthesis and Structure of

Lutz M. Engelhardt; Ulrich Kynast; Colin L. Raston; Allan H. White

doi:10.1002/anie.198706811

Alkylaluminum Cations: Synthesis and Structure of

Lutz M. Engelhardt, Ulrich Kynast, Colin L. Raston, Allan H. White

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Abstract

A distorted tetrahedral environment, a bond length typical for terminal AlC bonds, and unusually small AlN distances characterize the cation 1, which is formed on addition of AlCl₃ to the corresponding chloride. The AlN distances show that Lewis acid‐base interactions are required for the stabilization of a dialkylaluminum ion. (Figure Presented.)

Original language	English
Pages (from-to)	681-682
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	26
Issue number	7
DOIs	https://doi.org/10.1002/anie.198706811
Publication status	Published - Jul 1987
Externally published	Yes

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title = "Alkylaluminum Cations: Synthesis and Structure of",

abstract = "A distorted tetrahedral environment, a bond length typical for terminal AlC bonds, and unusually small AlN distances characterize the cation 1, which is formed on addition of AlCl3 to the corresponding chloride. The AlN distances show that Lewis acid‐base interactions are required for the stabilization of a dialkylaluminum ion. (Figure Presented.)",

author = "Engelhardt, {Lutz M.} and Ulrich Kynast and Raston, {Colin L.} and White, {Allan H.}",

year = "1987",

month = jul,

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language = "English",

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AU - Engelhardt, Lutz M.

AU - Kynast, Ulrich

AU - Raston, Colin L.

AU - White, Allan H.

PY - 1987/7

Y1 - 1987/7

N2 - A distorted tetrahedral environment, a bond length typical for terminal AlC bonds, and unusually small AlN distances characterize the cation 1, which is formed on addition of AlCl3 to the corresponding chloride. The AlN distances show that Lewis acid‐base interactions are required for the stabilization of a dialkylaluminum ion. (Figure Presented.)

AB - A distorted tetrahedral environment, a bond length typical for terminal AlC bonds, and unusually small AlN distances characterize the cation 1, which is formed on addition of AlCl3 to the corresponding chloride. The AlN distances show that Lewis acid‐base interactions are required for the stabilization of a dialkylaluminum ion. (Figure Presented.)

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DO - 10.1002/anie.198706811

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Alkylaluminum Cations: Synthesis and Structure of

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