Alkylaluminum Cations: Synthesis and Structure of

Lutz M. Engelhardt, Ulrich Kynast, Colin L. Raston, Allan H. White

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract


A distorted tetrahedral environment, a bond length typical for terminal AlC bonds, and unusually small AlN distances characterize the cation 1, which is formed on addition of AlCl3 to the corresponding chloride. The AlN distances show that Lewis acid‐base interactions are required for the stabilization of a dialkylaluminum ion. (Figure Presented.)

Original languageEnglish
Pages (from-to)681-682
Number of pages2
JournalAngewandte Chemie International Edition in English
Volume26
Issue number7
DOIs
Publication statusPublished - Jul 1987
Externally publishedYes

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