Alkylation of (As, Sb, Bi)Cl3: Formation of [(As, Sb, Bi)RCl2], (E)-[BiR(CH2CH=C)(SiMe3)(C 5H4N-2)] and 2-CH(SiMe3)2C 5H4N-5-R [r = C(SiMe3)2C 5H4N-2]

Cameron Jones; Lutz M. Engelhardt; Peter C. Junk; David S. Hutchings; Wyona C. Patalinghug; Colin L. Raston; Allan H. White

doi:10.1039/C39910001560

Alkylation of (As, Sb, Bi)Cl₃: Formation of [(As, Sb, Bi)RCl₂], (E)-[BiR(CH₂CH=C)(SiMe₃)(C ₅H₄N-2)] and 2-CH(SiMe₃)₂C ₅H₄N-5-R [r = C(SiMe₃)₂C ₅H₄N-2]

Cameron Jones, Lutz M. Engelhardt, Peter C. Junk, David S. Hutchings, Wyona C. Patalinghug, Colin L. Raston, Allan H. White

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Abstract

Monomeric alkyldichloro-antimony(III) and -bismuth(III) compounds [MRCl₂], R = C(SiMe₃)₂C₅H ₄N-2′, and the thermally unstable arsenic(III) analogue are accessible from the appropriate group 15 trichloride and LiR in diethyl ether; treating BiCl₃ with two and three equivalents of LiR in tetrahydrofuran (THF) yields (E)-[BiR(CH₂CH=C)(SiMe ₃)(C₅H₄N-2)] where the C₂ insertion-SiMe₃ elimination fragment originates from THF, and the 'head-to-tail' alkyl coupled species, 2-CH(SiMe₃)₂C ₅H₄N-5-R.

Original language	English
Pages (from-to)	1560-1562
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/C39910001560
Publication status	Published - 1 Nov 1991
Externally published	Yes

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Jones, C., Engelhardt, L. M., Junk, P. C., Hutchings, D. S., Patalinghug, W. C., Raston, C. L., & White, A. H. (1991). Alkylation of (As, Sb, Bi)Cl₃: Formation of [(As, Sb, Bi)RCl₂], (E)-[BiR(CH₂CH=C)(SiMe₃)(C ₅H₄N-2)] and 2-CH(SiMe₃)₂C ₅H₄N-5-R [r = C(SiMe₃)₂C ₅H₄N-2]. Journal of the Chemical Society, Chemical Communications, (21), 1560-1562. https://doi.org/10.1039/C39910001560

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title = "Alkylation of (As, Sb, Bi)Cl3: Formation of [(As, Sb, Bi)RCl2], (E)-[BiR(CH2CH=C)(SiMe3)(C 5H4N-2)] and 2-CH(SiMe3)2C 5H4N-5-R [r = C(SiMe3)2C 5H4N-2]",
abstract = "Monomeric alkyldichloro-antimony(III) and -bismuth(III) compounds [MRCl2], R = C(SiMe3)2C5H 4N-2′, and the thermally unstable arsenic(III) analogue are accessible from the appropriate group 15 trichloride and LiR in diethyl ether; treating BiCl3 with two and three equivalents of LiR in tetrahydrofuran (THF) yields (E)-[BiR(CH2CH=C)(SiMe 3)(C5H4N-2)] where the C2 insertion-SiMe3 elimination fragment originates from THF, and the 'head-to-tail' alkyl coupled species, 2-CH(SiMe3)2C 5H4N-5-R.",
author = "Cameron Jones and Engelhardt, {Lutz M.} and Junk, {Peter C.} and Hutchings, {David S.} and Patalinghug, {Wyona C.} and Raston, {Colin L.} and White, {Allan H.}",
year = "1991",
month = nov,
day = "1",
doi = "10.1039/C39910001560",
language = "English",
pages = "1560--1562",
journal = "Journal of the Chemical Society, Chemical Communications",
issn = "0022-4936",
publisher = "Chemical Society",
number = "21",
}

Alkylation of (As, Sb, Bi)Cl₃: Formation of [(As, Sb, Bi)RCl₂], (E)-[BiR(CH₂CH=C)(SiMe₃)(C ₅H₄N-2)] and 2-CH(SiMe₃)₂C ₅H₄N-5-R [r = C(SiMe₃)₂C ₅H₄N-2]. / Jones, Cameron; Engelhardt, Lutz M.; Junk, Peter C. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 21, 01.11.1991, p. 1560-1562.
Research output: Contribution to journal › Article › peer-review

TY - JOUR
T1 - Alkylation of (As, Sb, Bi)Cl3
T2 - Formation of [(As, Sb, Bi)RCl2], (E)-[BiR(CH2CH=C)(SiMe3)(C 5H4N-2)] and 2-CH(SiMe3)2C 5H4N-5-R [r = C(SiMe3)2C 5H4N-2]
AU - Jones, Cameron
AU - Engelhardt, Lutz M.
AU - Junk, Peter C.
AU - Hutchings, David S.
AU - Patalinghug, Wyona C.
AU - Raston, Colin L.
AU - White, Allan H.
PY - 1991/11/1
Y1 - 1991/11/1
N2 - Monomeric alkyldichloro-antimony(III) and -bismuth(III) compounds [MRCl2], R = C(SiMe3)2C5H 4N-2′, and the thermally unstable arsenic(III) analogue are accessible from the appropriate group 15 trichloride and LiR in diethyl ether; treating BiCl3 with two and three equivalents of LiR in tetrahydrofuran (THF) yields (E)-[BiR(CH2CH=C)(SiMe 3)(C5H4N-2)] where the C2 insertion-SiMe3 elimination fragment originates from THF, and the 'head-to-tail' alkyl coupled species, 2-CH(SiMe3)2C 5H4N-5-R.
AB - Monomeric alkyldichloro-antimony(III) and -bismuth(III) compounds [MRCl2], R = C(SiMe3)2C5H 4N-2′, and the thermally unstable arsenic(III) analogue are accessible from the appropriate group 15 trichloride and LiR in diethyl ether; treating BiCl3 with two and three equivalents of LiR in tetrahydrofuran (THF) yields (E)-[BiR(CH2CH=C)(SiMe 3)(C5H4N-2)] where the C2 insertion-SiMe3 elimination fragment originates from THF, and the 'head-to-tail' alkyl coupled species, 2-CH(SiMe3)2C 5H4N-5-R.
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DO - 10.1039/C39910001560
M3 - Article
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SN - 0022-4936
SP - 1560
EP - 1562
JO - Journal of the Chemical Society, Chemical Communications
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Alkylation of (As, Sb, Bi)Cl3: Formation of [(As, Sb, Bi)RCl2], (E)-[BiR(CH2CH=C)(SiMe3)(C 5H4N-2)] and 2-CH(SiMe3)2C 5H4N-5-R [r = C(SiMe3)2C 5H4N-2]

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Alkylation of (As, Sb, Bi)Cl₃: Formation of [(As, Sb, Bi)RCl₂], (E)-[BiR(CH₂CH=C)(SiMe₃)(C ₅H₄N-2)] and 2-CH(SiMe₃)₂C ₅H₄N-5-R [r = C(SiMe₃)₂C ₅H₄N-2]