Amido→azaallyl transformation in sodium amide complexes of (S)-α-(methylbenzyl)benzylamine

Philip C. Andrews; Peter J. Duggan; Gary D. Fallen; Tom D. McCarthy; Anna C. Peatt

doi:10.1039/b003826l

Amido→azaallyl transformation in sodium amide complexes of (S)-α-(methylbenzyl)benzylamine

Philip C. Andrews, Peter J. Duggan, Gary D. Fallen, Tom D. McCarthy, Anna C. Peatt

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

The reaction of (S)-{[(Ph(Me)CH)(PhCH₂)]NNa}_n with pmdeta (N,N,N,′N,′N″-pentamethyldiethylenetriamine) produces red/green dichroic crystals of the azaallylic complexes {[Ph(Me)CNC(H)Ph]Na-pmdeta}, 3, and {[(PhCH)₂N]Na-pmdeta}, 2; by X-ray diffraction 3 is found to be monomeric and structurally similar to the previously characterised 2.

Original language	English
Pages (from-to)	2505-2507
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	15
DOIs	https://doi.org/10.1039/b003826l
Publication status	Published - 2000
Externally published	Yes

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title = "Amido→azaallyl transformation in sodium amide complexes of (S)-α-(methylbenzyl)benzylamine",

abstract = "The reaction of (S)-{[(Ph(Me)CH)(PhCH2)]NNa}n with pmdeta (N,N,N,′N,′N″-pentamethyldiethylenetriamine) produces red/green dichroic crystals of the azaallylic complexes {[Ph(Me)CNC(H)Ph]Na-pmdeta}, 3, and {[(PhCH)2N]Na-pmdeta}, 2; by X-ray diffraction 3 is found to be monomeric and structurally similar to the previously characterised 2.",

author = "Andrews, {Philip C.} and Duggan, {Peter J.} and Fallen, {Gary D.} and McCarthy, {Tom D.} and Peatt, {Anna C.}",

year = "2000",

doi = "10.1039/b003826l",

language = "English",

pages = "2505--2507",

journal = "Journal of the Chemical Society, Dalton Transactions",

issn = "1470-479X",

publisher = "Royal Society of Chemistry",

number = "15",

}

TY - JOUR

T1 - Amido→azaallyl transformation in sodium amide complexes of (S)-α-(methylbenzyl)benzylamine

AU - Andrews, Philip C.

AU - Duggan, Peter J.

AU - Fallen, Gary D.

AU - McCarthy, Tom D.

AU - Peatt, Anna C.

PY - 2000

Y1 - 2000

N2 - The reaction of (S)-{[(Ph(Me)CH)(PhCH2)]NNa}n with pmdeta (N,N,N,′N,′N″-pentamethyldiethylenetriamine) produces red/green dichroic crystals of the azaallylic complexes {[Ph(Me)CNC(H)Ph]Na-pmdeta}, 3, and {[(PhCH)2N]Na-pmdeta}, 2; by X-ray diffraction 3 is found to be monomeric and structurally similar to the previously characterised 2.

AB - The reaction of (S)-{[(Ph(Me)CH)(PhCH2)]NNa}n with pmdeta (N,N,N,′N,′N″-pentamethyldiethylenetriamine) produces red/green dichroic crystals of the azaallylic complexes {[Ph(Me)CNC(H)Ph]Na-pmdeta}, 3, and {[(PhCH)2N]Na-pmdeta}, 2; by X-ray diffraction 3 is found to be monomeric and structurally similar to the previously characterised 2.

UR - http://www.scopus.com/inward/record.url?scp=0002088940&partnerID=8YFLogxK

U2 - 10.1039/b003826l

DO - 10.1039/b003826l

M3 - Article

AN - SCOPUS:0002088940

SN - 1470-479X

SP - 2505

EP - 2507

JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 15

ER -

Amido→azaallyl transformation in sodium amide complexes of (S)-α-(methylbenzyl)benzylamine

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