An unprecedented hexapotassium-hexamagnesium 24-membered macrocyclic amide: A polymetallic cationic host to six monodeprotonated arene anions

Philip C. Andrews; Alan R. Kennedy; Robert E. Mulvey; Colin L. Raston; Brett A. Roberts; René B. Rowlings

doi:10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D

An unprecedented hexapotassium-hexamagnesium 24-membered macrocyclic amide: A polymetallic cationic host to six monodeprotonated arene anions

Philip C. Andrews, Alan R. Kennedy, Robert E. Mulvey, Colin L. Raston, Brett A. Roberts, René B. Rowlings

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

Six arene anions in a cationic [K₆Mg₆N₁₂]⁶⁺ ring (see picture, arene = benzene) are reported in the mixed-metal macrocyclic amide of 24 (!) ring atoms. The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.

Original language	English
Pages (from-to)	1960-1962
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	11
DOIs	https://doi.org/10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D
Publication status	Published - 2 Jun 2000
Externally published	Yes

Keywords

Alkali metals
Alkaline earth metals
Amides
Macrocycles
Template synthesis

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10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-DLicence: In Copyright

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Andrews, P. C., Kennedy, A. R., Mulvey, R. E., Raston, C. L., Roberts, B. A., & Rowlings, R. B. (2000). An unprecedented hexapotassium-hexamagnesium 24-membered macrocyclic amide: A polymetallic cationic host to six monodeprotonated arene anions. Angewandte Chemie - International Edition, 39(11), 1960-1962. https://doi.org/10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D

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title = "An unprecedented hexapotassium-hexamagnesium 24-membered macrocyclic amide: A polymetallic cationic host to six monodeprotonated arene anions",

abstract = "Six arene anions in a cationic [K6Mg6N12]6+ ring (see picture, arene = benzene) are reported in the mixed-metal macrocyclic amide of 24 (!) ring atoms. The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.",

keywords = "Alkali metals, Alkaline earth metals, Amides, Macrocycles, Template synthesis",

author = "Andrews, {Philip C.} and Kennedy, {Alan R.} and Mulvey, {Robert E.} and Raston, {Colin L.} and Roberts, {Brett A.} and Rowlings, {Ren{\'e} B.}",

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doi = "10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D",

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Andrews, PC, Kennedy, AR, Mulvey, RE, Raston, CL, Roberts, BA & Rowlings, RB 2000, 'An unprecedented hexapotassium-hexamagnesium 24-membered macrocyclic amide: A polymetallic cationic host to six monodeprotonated arene anions', Angewandte Chemie - International Edition, vol. 39, no. 11, pp. 1960-1962. https://doi.org/10.1002/1521-3773(20000602)39:11<1960::AID-ANIE1960>3.0.CO;2-D

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T1 - An unprecedented hexapotassium-hexamagnesium 24-membered macrocyclic amide

T2 - A polymetallic cationic host to six monodeprotonated arene anions

AU - Andrews, Philip C.

AU - Kennedy, Alan R.

AU - Mulvey, Robert E.

AU - Raston, Colin L.

AU - Roberts, Brett A.

AU - Rowlings, René B.

PY - 2000/6/2

Y1 - 2000/6/2

N2 - Six arene anions in a cationic [K6Mg6N12]6+ ring (see picture, arene = benzene) are reported in the mixed-metal macrocyclic amide of 24 (!) ring atoms. The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.

AB - Six arene anions in a cationic [K6Mg6N12]6+ ring (see picture, arene = benzene) are reported in the mixed-metal macrocyclic amide of 24 (!) ring atoms. The macrocycle is produced through a very effective synthesis, in which the anions are selectively monodeprotonated.

KW - Alkali metals

KW - Alkaline earth metals

KW - Amides

KW - Macrocycles

KW - Template synthesis

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M3 - Article

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VL - 39

SP - 1960

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 11

ER -

An unprecedented hexapotassium-hexamagnesium 24-membered macrocyclic amide: A polymetallic cationic host to six monodeprotonated arene anions

Abstract

Keywords

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