Approaching a cluster of aluminium(III) selenide: [Al4Se5(H)2(NMe3)4]

Peter D. Godfrey; Colin L. Raston; Brian W. Skelton; Vicki Anne Tolhurst; Allan H. White

doi:10.1039/a703324i

Approaching a cluster of aluminium(III) selenide: [Al₄Se₅(H)₂(NMe₃)₄]

Peter D. Godfrey, Colin L. Raston, Brian W. Skelton, Vicki Anne Tolhurst, Allan H. White

Research output: Contribution to journal › Article

9 Citations (Scopus)

Abstract

The reaction of trans-[{Me₃N(H)Al(μ-Se)}₂] with N,N,N′,N″,N″-pentamethyldiethylenetriamine (pmdeta) in toluene affords the tetranuclear, alane selenide cluster [Al₄Se₅(H)₂(NMe₃)₄] (structurally authenticated and ab initio modelled), and with PhTeTePh yields a mixed chalcogenide trans-[{Me₃N(PhTe)Al(μ-Se)}₂].

Original language	English
Pages (from-to)	2235-2236
Number of pages	2
Journal	Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/a703324i
Publication status	Published - 1 Jan 1997
Externally published	Yes

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Godfrey, P. D., Raston, C. L., Skelton, B. W., Tolhurst, V. A., & White, A. H. (1997). Approaching a cluster of aluminium(III) selenide: [Al₄Se₅(H)₂(NMe₃)₄]. Chemical Communications, (22), 2235-2236. https://doi.org/10.1039/a703324i

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abstract = "The reaction of trans-[{Me3N(H)Al(μ-Se)}2] with N,N,N′,N″,N″-pentamethyldiethylenetriamine (pmdeta) in toluene affords the tetranuclear, alane selenide cluster [Al4Se5(H)2(NMe3)4] (structurally authenticated and ab initio modelled), and with PhTeTePh yields a mixed chalcogenide trans-[{Me3N(PhTe)Al(μ-Se)}2].",

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AU - Tolhurst, Vicki Anne

AU - White, Allan H.

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AB - The reaction of trans-[{Me3N(H)Al(μ-Se)}2] with N,N,N′,N″,N″-pentamethyldiethylenetriamine (pmdeta) in toluene affords the tetranuclear, alane selenide cluster [Al4Se5(H)2(NMe3)4] (structurally authenticated and ab initio modelled), and with PhTeTePh yields a mixed chalcogenide trans-[{Me3N(PhTe)Al(μ-Se)}2].

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