Approaching a cluster of aluminium(III) selenide: [Al4Se5(H)2(NMe3)4]

Peter D. Godfrey; Colin L. Raston; Brian W. Skelton; Vicki Anne Tolhurst; Allan H. White

doi:10.1039/a703324i

Approaching a cluster of aluminium(III) selenide: [Al₄Se₅(H)₂(NMe₃)₄]

Peter D. Godfrey, Colin L. Raston, Brian W. Skelton, Vicki Anne Tolhurst, Allan H. White

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The reaction of trans-[{Me₃N(H)Al(μ-Se)}₂] with N,N,N′,N″,N″-pentamethyldiethylenetriamine (pmdeta) in toluene affords the tetranuclear, alane selenide cluster [Al₄Se₅(H)₂(NMe₃)₄] (structurally authenticated and ab initio modelled), and with PhTeTePh yields a mixed chalcogenide trans-[{Me₃N(PhTe)Al(μ-Se)}₂].

Original language	English
Pages (from-to)	2235-2236
Number of pages	2
Journal	Chemical Communications
Issue number	22
DOIs	https://doi.org/10.1039/a703324i
Publication status	Published - 1 Jan 1997
Externally published	Yes

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title = "Approaching a cluster of aluminium(III) selenide: [Al4Se5(H)2(NMe3)4]",

abstract = "The reaction of trans-[{Me3N(H)Al(μ-Se)}2] with N,N,N′,N″,N″-pentamethyldiethylenetriamine (pmdeta) in toluene affords the tetranuclear, alane selenide cluster [Al4Se5(H)2(NMe3)4] (structurally authenticated and ab initio modelled), and with PhTeTePh yields a mixed chalcogenide trans-[{Me3N(PhTe)Al(μ-Se)}2].",

author = "Godfrey, {Peter D.} and Raston, {Colin L.} and Skelton, {Brian W.} and Tolhurst, {Vicki Anne} and White, {Allan H.}",

year = "1997",

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doi = "10.1039/a703324i",

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T1 - Approaching a cluster of aluminium(III) selenide

T2 - [Al4Se5(H)2(NMe3)4]

AU - Godfrey, Peter D.

AU - Raston, Colin L.

AU - Skelton, Brian W.

AU - Tolhurst, Vicki Anne

AU - White, Allan H.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - The reaction of trans-[{Me3N(H)Al(μ-Se)}2] with N,N,N′,N″,N″-pentamethyldiethylenetriamine (pmdeta) in toluene affords the tetranuclear, alane selenide cluster [Al4Se5(H)2(NMe3)4] (structurally authenticated and ab initio modelled), and with PhTeTePh yields a mixed chalcogenide trans-[{Me3N(PhTe)Al(μ-Se)}2].

AB - The reaction of trans-[{Me3N(H)Al(μ-Se)}2] with N,N,N′,N″,N″-pentamethyldiethylenetriamine (pmdeta) in toluene affords the tetranuclear, alane selenide cluster [Al4Se5(H)2(NMe3)4] (structurally authenticated and ab initio modelled), and with PhTeTePh yields a mixed chalcogenide trans-[{Me3N(PhTe)Al(μ-Se)}2].

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U2 - 10.1039/a703324i

DO - 10.1039/a703324i

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JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 22

ER -

Approaching a cluster of aluminium(III) selenide: [Al₄Se₅(H)₂(NMe₃)₄]

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