Aryl ring dynamics in bis-succinimido-cyclophanes

Douglas N. Butler; Muhong Shang; David Mann; Martin R. Johnston

doi:10.3998/ark.5550190.0002.c04

Aryl ring dynamics in bis-succinimido-cyclophanes

Douglas N. Butler, Muhong Shang, David Mann, Martin R. Johnston

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The rotation or flipping barriers for the aryl rings of a series of p- and m-xylenes and related arenes mounted between the two nitrogen atoms of a rigid, bis-succinimido hexacyclic molecular 'rack' (eg 16) have been measured using dynamic NMR (DNMR) methods and compared with relevant literature values.

Original language	English
Pages (from-to)	27-34
Number of pages	8
Journal	Arkivoc
Volume	2001
Issue number	12
DOIs	https://doi.org/10.3998/ark.5550190.0002.c04
Publication status	Published - 2001
Externally published	Yes

Keywords

Aryl rings
Dynamic nmr
Flipping barriers
Rotation barriers
Succinimido-cyclophanes

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10.3998/ark.5550190.0002.c04Licence: In Copyright

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AU - Shang, Muhong

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AU - Johnston, Martin R.

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AB - The rotation or flipping barriers for the aryl rings of a series of p- and m-xylenes and related arenes mounted between the two nitrogen atoms of a rigid, bis-succinimido hexacyclic molecular 'rack' (eg 16) have been measured using dynamic NMR (DNMR) methods and compared with relevant literature values.

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KW - Dynamic nmr

KW - Flipping barriers

KW - Rotation barriers

KW - Succinimido-cyclophanes

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Aryl ring dynamics in bis-succinimido-cyclophanes

Abstract

Keywords

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