Authentication of a sodium primary phosphide: Synthesis and crystal structure of [Na{PH(C6H11)}(pmdeta)]2 (pmdeta=N,N,N′,N″,N″-pentamethyldiethylenetriamine)

George A. Koutsantonis, Philip C. Andrews, Colin L. Raston

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

The reaction of the primary phosphine PH2(C6H 11) with NaBun in the presence of pmdeta gives the first sodium phosphide containing simple organo substituents [Na{PH(C 6H11)}(pmdeta)]2 1 (pmdeta=N,N,N′, N″,N″-pentamethyldiethylenetriamine) to be structurally characterised.

Original languageEnglish
Pages (from-to)47-48
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number1
DOIs
Publication statusPublished - 7 Jan 1995
Externally publishedYes

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