Authentication of a sodium primary phosphide: Synthesis and crystal structure of [Na{PH(C6H11)}(pmdeta)]2 (pmdeta=N,N,N′,N″,N″-pentamethyldiethylenetriamine)

George A. Koutsantonis, Philip C. Andrews, Colin L. Raston

Research output: Contribution to journalArticlepeer-review

32 Citations (Scopus)

Abstract

The reaction of the primary phosphine PH2(C6H 11) with NaBun in the presence of pmdeta gives the first sodium phosphide containing simple organo substituents [Na{PH(C 6H11)}(pmdeta)]2 1 (pmdeta=N,N,N′, N″,N″-pentamethyldiethylenetriamine) to be structurally characterised.

Original languageEnglish
Pages (from-to)47-48
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number1
DOIs
Publication statusPublished - 7 Jan 1995
Externally publishedYes

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