Authentication of a sodium primary phosphide: Synthesis and crystal structure of [Na{PH(C6H11)}(pmdeta)]2 (pmdeta=N,N,N′,N″,N″-pentamethyldiethylenetriamine)

George A. Koutsantonis; Philip C. Andrews; Colin L. Raston

doi:10.1039/C39950000047

Authentication of a sodium primary phosphide: Synthesis and crystal structure of [Na{PH(C₆H₁₁)}(pmdeta)]₂ (pmdeta=N,N,N′,N″,N″-pentamethyldiethylenetriamine)

George A. Koutsantonis, Philip C. Andrews, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

The reaction of the primary phosphine PH₂(C₆H ₁₁) with NaBuⁿ in the presence of pmdeta gives the first sodium phosphide containing simple organo substituents [Na{PH(C ₆H₁₁)}(pmdeta)]₂ 1 (pmdeta=N,N,N′, N″,N″-pentamethyldiethylenetriamine) to be structurally characterised.

Original language	English
Pages (from-to)	47-48
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/C39950000047
Publication status	Published - 7 Jan 1995
Externally published	Yes

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title = "Authentication of a sodium primary phosphide: Synthesis and crystal structure of [Na{PH(C6H11)}(pmdeta)]2 (pmdeta=N,N,N′,N″,N″-pentamethyldiethylenetriamine)",

abstract = "The reaction of the primary phosphine PH2(C6H 11) with NaBun in the presence of pmdeta gives the first sodium phosphide containing simple organo substituents [Na{PH(C 6H11)}(pmdeta)]2 1 (pmdeta=N,N,N′, N″,N″-pentamethyldiethylenetriamine) to be structurally characterised.",

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Authentication of a sodium primary phosphide: Synthesis and crystal structure of [Na{PH(C₆H₁₁)}(pmdeta)]₂ (pmdeta=N,N,N′,N″,N″-pentamethyldiethylenetriamine). / Koutsantonis, George A.; Andrews, Philip C.; Raston, Colin L.
In: Journal of the Chemical Society, Chemical Communications, No. 1, 07.01.1995, p. 47-48.

Research output: Contribution to journal › Article › peer-review

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T1 - Authentication of a sodium primary phosphide

T2 - Synthesis and crystal structure of [Na{PH(C6H11)}(pmdeta)]2 (pmdeta=N,N,N′,N″,N″-pentamethyldiethylenetriamine)

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AU - Raston, Colin L.

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AB - The reaction of the primary phosphine PH2(C6H 11) with NaBun in the presence of pmdeta gives the first sodium phosphide containing simple organo substituents [Na{PH(C 6H11)}(pmdeta)]2 1 (pmdeta=N,N,N′, N″,N″-pentamethyldiethylenetriamine) to be structurally characterised.

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Authentication of a sodium primary phosphide: Synthesis and crystal structure of [Na{PH(C₆H₁₁)}(pmdeta)]₂ (pmdeta=N,N,N′,N″,N″-pentamethyldiethylenetriamine)

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