Axially asymmetric metal alkyls. Part 2. Synthesis of the di-Grignard reagent [{Mg(thf)nCl}2R] [thf = tetrahydrofuran, R = (2-CH2C6H4)22-] and 6,7-dihydro-5H-dibenzo[c,e]-silepines and -stannepines; X-ray crystal structures of [SnPh2R] and δ-SS- and λ-RR-[SnPh2{[2-CH(SiMe3)C6H 4]2}]and λ-RR-[SnPh2{[2-CH(SiMe3)C6H 4]2}]: and λ-RR-[SnPh2{[2-CH(SiMe3)C6H 4]2}]

Lutz M. Engelhardt, Wing Por Leung, Colin L. Raston, Paul Twiss, Allan H. White

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)

Fingerprint

Dive into the research topics of 'Axially asymmetric metal alkyls. Part 2. Synthesis of the di-Grignard reagent [{Mg(thf)nCl}2R] [thf = tetrahydrofuran, R = (2-CH2C6H4)22-] and 6,7-dihydro-5H-dibenzo[c,e]-silepines and -stannepines; X-ray crystal structures of [SnPh2R] and δ-SS- and λ-RR-[SnPh2{[2-CH(SiMe3)C6H 4]2}]and λ-RR-[SnPh2{[2-CH(SiMe3)C6H 4]2}]: and λ-RR-[SnPh2{[2-CH(SiMe3)C6H 4]2}]'. Together they form a unique fingerprint.

Chemical Compounds