Axially asymmetric metal alkyls. Part 3. Chemical, electrochemical, and structural studies of group 5A d0,1,2 metallepines [M{(2-CH2C6H4)2}(η-C 5H5)2]z (M = Nb or Ta; z = 1-, 0, or 1+): synthesis of [Nb{2-CH2(C6H4) 2Me-2′}X-(η-C5H5)2] (X = Cl or CO) and [{(η-C5H5)2ClV}2{(2-CH 2C6H4)2}], and electrochemistry of [M(CH2Ph)2-nCln(η-C5H 5)2] (n = 0, M = Nb, or Ta; n = 1, M = V)synthesis of [Nb{2-CH2(C6H4) 2Me-2′}X-(η-C5H5)2] (X = Cl or CO) and [{(η-C5H5)2ClV}2{(2-CH 2C6H4)2}], and electrochemistry of [M(CH2Ph)2-nCln(η-C5H 5)2] (n = 0, M = Nb, or Ta; n = 1, M = V)

Stuart I. Bailey, Lutz M. Engelhardt, Wing Por Leung, Colin L. Raston, Ian M. Ritchie, Allan H. White

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Dive into the research topics of 'Axially asymmetric metal alkyls. Part 3. Chemical, electrochemical, and structural studies of group 5A d<sup>0,1,2</sup> metallepines [M{(2-CH<sub>2</sub>C<sub>6</sub>H<sub>4</sub>)<sub>2</sub>}(η-C <sub>5</sub>H<sub>5</sub>)<sub>2</sub>]<sup>z</sup> (M = Nb or Ta; z = 1-, 0, or 1+): synthesis of [Nb{2-CH2(C6H4) 2Me-2′}X-(η-C5H5)2] (X = Cl or CO) and [{(η-C5H5)2ClV}2{(2-CH 2C6H4)2}], and electrochemistry of [M(CH2Ph)2-nCln(η-C5H 5)2] (n = 0, M = Nb, or Ta; n = 1, M = V)synthesis of [Nb{2-CH2(C6H4) 2Me-2′}X-(η-C5H5)2] (X = Cl or CO) and [{(η-C5H5)2ClV}2{(2-CH 2C6H4)2}], and electrochemistry of [M(CH2Ph)2-nCln(η-C5H 5)2] (n = 0, M = Nb, or Ta; n = 1, M = V)'. Together they form a unique fingerprint.

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