Axially asymmetric metal alkyls. Part 5. Synthesis and reduction to ZrIII species of group 4 metallepines [ML(η-C5H5)2] [L = (2-CHRC6H4)22-, R = H, M = Ti, Zr, or Hf)], isomers of [ZrL(η-C5H5)2] (R = SiMe3), and... ... meso-[M{1,8-(CHSiMe3)2C10H6}(η-C5H5)2](M = Zr or Hf); X-ray crystal structures of [TiL(η-C5H5)2](R = H) and λ- and δ-RS-[ZrL(η-C5H5)2](R = SiMe3)

Lutz M. Engelhardt, Wing Por Leung, Rocco I. Papasergio, Colin L. Raston, Paul Twiss, Allan H. White

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Fingerprint

Dive into the research topics of 'Axially asymmetric metal alkyls. Part 5. Synthesis and reduction to Zr<sup>III</sup> species of group 4 metallepines [ML(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>] [L = (2-CHRC<sub>6</sub>H<sub>4</sub>)<sub>2</sub><sup>2-</sup>, R = H, M = Ti, Zr, or Hf)], isomers of [ZrL(η-C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>] (R = SiMe<sub>3</sub>), and... ... meso-[M{1,8-(CHSiMe3)2C10H6}(η-C5H5)2](M = Zr or Hf); X-ray crystal structures of [TiL(η-C5H5)2](R = H) and λ- and δ-RS-[ZrL(η-C5H5)2](R = SiMe3)'. Together they form a unique fingerprint.

Chemical Compounds