Bis-amido- complexes of heavier group 15 metal chlorides with the sterically hindered, N-functionalised amido ligand, [{2-(6-Me)C5H3N}NSiMe3]-

Colin L. Raston; Brian W. Skelton; Vicki Anne Tolhurst; Allan H. White

doi:10.1016/S0277-5387(97)00243-X

Bis-amido- complexes of heavier group 15 metal chlorides with the sterically hindered, N-functionalised amido ligand, [{2-(6-Me)C₅H₃N}NSiMe₃]^-

Colin L. Raston, Brian W. Skelton, Vicki Anne Tolhurst, Allan H. White

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

The reaction of the lithium amide, [2-(6-methyl)pyridyl]trimethylsilylamido-lithium, with antimony(III) or bismuth(III) trichloride in diethyl ether gives the bis-amido antimony(III) or bismuth(III) chloride [{2-(6-Me)C₅H₃N} NSiMe₃]MCl, [M =Sb (1) or Bi (2)] as colourless or yellow prisms respectively. The antimony complex is monomeric in the solid state whereas the bismuth complex is dimeric with bridging chlorides.

Original language	English
Pages (from-to)	935-942
Number of pages	8
Journal	POLYHEDRON
Volume	17
Issue number	5-6
DOIs	https://doi.org/10.1016/S0277-5387(97)00243-X
Publication status	Published - 1 Jan 1998
Externally published	Yes

Keywords

Amido-complexes
Antimony(III)
Bismuth(III)
Chloro
Lithium
N-functionalised

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title = "Bis-amido- complexes of heavier group 15 metal chlorides with the sterically hindered, N-functionalised amido ligand, [{2-(6-Me)C5H3N}NSiMe3]-",

abstract = "The reaction of the lithium amide, [2-(6-methyl)pyridyl]trimethylsilylamido-lithium, with antimony(III) or bismuth(III) trichloride in diethyl ether gives the bis-amido antimony(III) or bismuth(III) chloride [{2-(6-Me)C5H3N} NSiMe3]MCl, [M =Sb (1) or Bi (2)] as colourless or yellow prisms respectively. The antimony complex is monomeric in the solid state whereas the bismuth complex is dimeric with bridging chlorides.",

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T1 - Bis-amido- complexes of heavier group 15 metal chlorides with the sterically hindered, N-functionalised amido ligand, [{2-(6-Me)C5H3N}NSiMe3]-

AU - Raston, Colin L.

AU - Skelton, Brian W.

AU - Tolhurst, Vicki Anne

AU - White, Allan H.

PY - 1998/1/1

Y1 - 1998/1/1

N2 - The reaction of the lithium amide, [2-(6-methyl)pyridyl]trimethylsilylamido-lithium, with antimony(III) or bismuth(III) trichloride in diethyl ether gives the bis-amido antimony(III) or bismuth(III) chloride [{2-(6-Me)C5H3N} NSiMe3]MCl, [M =Sb (1) or Bi (2)] as colourless or yellow prisms respectively. The antimony complex is monomeric in the solid state whereas the bismuth complex is dimeric with bridging chlorides.

AB - The reaction of the lithium amide, [2-(6-methyl)pyridyl]trimethylsilylamido-lithium, with antimony(III) or bismuth(III) trichloride in diethyl ether gives the bis-amido antimony(III) or bismuth(III) chloride [{2-(6-Me)C5H3N} NSiMe3]MCl, [M =Sb (1) or Bi (2)] as colourless or yellow prisms respectively. The antimony complex is monomeric in the solid state whereas the bismuth complex is dimeric with bridging chlorides.

KW - Amido-complexes

KW - Antimony(III)

KW - Bismuth(III)

KW - Chloro

KW - Lithium

KW - N-functionalised

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U2 - 10.1016/S0277-5387(97)00243-X

DO - 10.1016/S0277-5387(97)00243-X

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SN - 0277-5387

VL - 17

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JO - POLYHEDRON

JF - POLYHEDRON

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ER -

Bis-amido- complexes of heavier group 15 metal chlorides with the sterically hindered, N-functionalised amido ligand, [{2-(6-Me)C₅H₃N}NSiMe₃]^-

Abstract

Keywords

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