TY - JOUR
T1 - Bis{1,4-bis(trimethylsilyl) buta-1,3-diene}cobalt
T2 - Synthesis and molecular structure
AU - Cloke, F. Geoffrey N.
AU - Gardiner, Michael G.
AU - Raston, Colin L.
AU - Simpson, Steven J.
PY - 1996/1/25
Y1 - 1996/1/25
N2 - Co-condensation of cobalt atoms with an excess of (E,E)-1,4-bis(trimethylsilyl)buta-1,3-diene in hexane at -196°C yields the homoleptic bis(butadiene) complex [Co{η-C4H4(SiMe3)2}2] (1) as the sole volatile product. Compound 1 was characterized by 1H NMR and EPR spectroscopy, mass spectrometry and a single-crystal X-ray structure determination.
AB - Co-condensation of cobalt atoms with an excess of (E,E)-1,4-bis(trimethylsilyl)buta-1,3-diene in hexane at -196°C yields the homoleptic bis(butadiene) complex [Co{η-C4H4(SiMe3)2}2] (1) as the sole volatile product. Compound 1 was characterized by 1H NMR and EPR spectroscopy, mass spectrometry and a single-crystal X-ray structure determination.
KW - Butadiene
KW - Cobalt
KW - Crystal structure
KW - Metal vapour synthesis
UR - http://www.scopus.com/inward/record.url?scp=0030600646&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(95)05736-9
DO - 10.1016/0022-328X(95)05736-9
M3 - Article
AN - SCOPUS:0030600646
SN - 0022-328X
VL - 507
SP - 245
EP - 248
JO - JOURNAL OF ORGANOMETALLIC CHEMISTRY
JF - JOURNAL OF ORGANOMETALLIC CHEMISTRY
IS - 1-2
ER -