Bis{1,4-bis(trimethylsilyl) buta-1,3-diene}cobalt: Synthesis and molecular structure

F. Geoffrey N. Cloke; Michael G. Gardiner; Colin L. Raston; Steven J. Simpson

doi:10.1016/0022-328X(95)05736-9

Bis{1,4-bis(trimethylsilyl) buta-1,3-diene}cobalt: Synthesis and molecular structure

F. Geoffrey N. Cloke
, Michael G. Gardiner
, Colin L. Raston
, Steven J. Simpson

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Co-condensation of cobalt atoms with an excess of (E,E)-1,4-bis(trimethylsilyl)buta-1,3-diene in hexane at -196°C yields the homoleptic bis(butadiene) complex [Co{η-C₄H₄(SiMe₃)₂}₂] (1) as the sole volatile product. Compound 1 was characterized by ¹H NMR and EPR spectroscopy, mass spectrometry and a single-crystal X-ray structure determination.

Original language	English
Pages (from-to)	245-248
Number of pages	4
Journal	JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume	507
Issue number	1-2
DOIs	https://doi.org/10.1016/0022-328X(95)05736-9
Publication status	Published - 25 Jan 1996
Externally published	Yes

Keywords

Butadiene
Cobalt
Crystal structure
Metal vapour synthesis

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10.1016/0022-328X(95)05736-9Licence: In Copyright

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title = "Bis\{1,4-bis(trimethylsilyl) buta-1,3-diene\}cobalt: Synthesis and molecular structure",

abstract = "Co-condensation of cobalt atoms with an excess of (E,E)-1,4-bis(trimethylsilyl)buta-1,3-diene in hexane at -196°C yields the homoleptic bis(butadiene) complex [Co\{η-C4H4(SiMe3)2\}2] (1) as the sole volatile product. Compound 1 was characterized by 1H NMR and EPR spectroscopy, mass spectrometry and a single-crystal X-ray structure determination.",

keywords = "Butadiene, Cobalt, Crystal structure, Metal vapour synthesis",

author = "Cloke, \{F. Geoffrey N.\} and Gardiner, \{Michael G.\} and Raston, \{Colin L.\} and Simpson, \{Steven J.\}",

year = "1996",

month = jan,

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doi = "10.1016/0022-328X(95)05736-9",

language = "English",

volume = "507",

pages = "245--248",

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TY - JOUR

T1 - Bis{1,4-bis(trimethylsilyl) buta-1,3-diene}cobalt

T2 - Synthesis and molecular structure

AU - Cloke, F. Geoffrey N.

AU - Gardiner, Michael G.

AU - Raston, Colin L.

AU - Simpson, Steven J.

PY - 1996/1/25

Y1 - 1996/1/25

N2 - Co-condensation of cobalt atoms with an excess of (E,E)-1,4-bis(trimethylsilyl)buta-1,3-diene in hexane at -196°C yields the homoleptic bis(butadiene) complex [Co{η-C4H4(SiMe3)2}2] (1) as the sole volatile product. Compound 1 was characterized by 1H NMR and EPR spectroscopy, mass spectrometry and a single-crystal X-ray structure determination.

AB - Co-condensation of cobalt atoms with an excess of (E,E)-1,4-bis(trimethylsilyl)buta-1,3-diene in hexane at -196°C yields the homoleptic bis(butadiene) complex [Co{η-C4H4(SiMe3)2}2] (1) as the sole volatile product. Compound 1 was characterized by 1H NMR and EPR spectroscopy, mass spectrometry and a single-crystal X-ray structure determination.

KW - Butadiene

KW - Cobalt

KW - Crystal structure

KW - Metal vapour synthesis

UR - https://www.scopus.com/pages/publications/0030600646

U2 - 10.1016/0022-328X(95)05736-9

DO - 10.1016/0022-328X(95)05736-9

M3 - Article

AN - SCOPUS:0030600646

SN - 0022-328X

VL - 507

SP - 245

EP - 248

JO - JOURNAL OF ORGANOMETALLIC CHEMISTRY

JF - JOURNAL OF ORGANOMETALLIC CHEMISTRY

IS - 1-2

ER -

Bis{1,4-bis(trimethylsilyl) buta-1,3-diene}cobalt: Synthesis and molecular structure

Abstract

Keywords

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