TY - JOUR
T1 - Calcium and strontium, and zinc (phenazine)-· species
AU - Jacobsen, Geraldine E.
AU - Raston, Colin L.
PY - 1990/9/18
Y1 - 1990/9/18
N2 - Calcium and strontium react with phenazine in tetrahydrofuran (THF) at ca 20 ° C to yield red solutions containing paramagnetic species based on (phenazine)-· (ESR characterization). Zinc reacts in THF in the presence of zinc chloride or bromide, or without metal halide in pyridine, to yield green or red ESR-active solutions also based on (phenazine)-·, and then, for the reaction in pyridine, a brown paramagnetic solid of composition Zn(phenazine)(pyridine)2.
AB - Calcium and strontium react with phenazine in tetrahydrofuran (THF) at ca 20 ° C to yield red solutions containing paramagnetic species based on (phenazine)-· (ESR characterization). Zinc reacts in THF in the presence of zinc chloride or bromide, or without metal halide in pyridine, to yield green or red ESR-active solutions also based on (phenazine)-·, and then, for the reaction in pyridine, a brown paramagnetic solid of composition Zn(phenazine)(pyridine)2.
UR - http://www.scopus.com/inward/record.url?scp=44949286716&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(90)85267-3
DO - 10.1016/0022-328X(90)85267-3
M3 - Article
AN - SCOPUS:44949286716
VL - 395
SP - c1-c4
JO - JOURNAL OF ORGANOMETALLIC CHEMISTRY
JF - JOURNAL OF ORGANOMETALLIC CHEMISTRY
SN - 0022-328X
IS - 1
ER -