Calcium and strontium, and zinc (phenazine)-· species

Geraldine E. Jacobsen; Colin L. Raston

doi:10.1016/0022-328X(90)85267-3

Calcium and strontium, and zinc (phenazine)^-· species

Geraldine E. Jacobsen
, Colin L. Raston

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Calcium and strontium react with phenazine in tetrahydrofuran (THF) at ca 20 ° C to yield red solutions containing paramagnetic species based on (phenazine)^-· (ESR characterization). Zinc reacts in THF in the presence of zinc chloride or bromide, or without metal halide in pyridine, to yield green or red ESR-active solutions also based on (phenazine)^-·, and then, for the reaction in pyridine, a brown paramagnetic solid of composition Zn(phenazine)(pyridine)₂.

Original language	English
Pages (from-to)	c1-c4
Number of pages	4
Journal	JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume	395
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(90)85267-3
Publication status	Published - 18 Sept 1990
Externally published	Yes

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title = "Calcium and strontium, and zinc (phenazine)-· species",

abstract = "Calcium and strontium react with phenazine in tetrahydrofuran (THF) at ca 20 ° C to yield red solutions containing paramagnetic species based on (phenazine)-· (ESR characterization). Zinc reacts in THF in the presence of zinc chloride or bromide, or without metal halide in pyridine, to yield green or red ESR-active solutions also based on (phenazine)-·, and then, for the reaction in pyridine, a brown paramagnetic solid of composition Zn(phenazine)(pyridine)2.",

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AU - Raston, Colin L.

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N2 - Calcium and strontium react with phenazine in tetrahydrofuran (THF) at ca 20 ° C to yield red solutions containing paramagnetic species based on (phenazine)-· (ESR characterization). Zinc reacts in THF in the presence of zinc chloride or bromide, or without metal halide in pyridine, to yield green or red ESR-active solutions also based on (phenazine)-·, and then, for the reaction in pyridine, a brown paramagnetic solid of composition Zn(phenazine)(pyridine)2.

AB - Calcium and strontium react with phenazine in tetrahydrofuran (THF) at ca 20 ° C to yield red solutions containing paramagnetic species based on (phenazine)-· (ESR characterization). Zinc reacts in THF in the presence of zinc chloride or bromide, or without metal halide in pyridine, to yield green or red ESR-active solutions also based on (phenazine)-·, and then, for the reaction in pyridine, a brown paramagnetic solid of composition Zn(phenazine)(pyridine)2.

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ER -

Calcium and strontium, and zinc (phenazine)^-· species

Abstract

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