Calix[5]arene: A versatile sublimate that displays gas sorption properties

Scott J. Dalgarno; Jian Tian; John E. Warren; Thomas E. Clark; Mohamed Makha; Colin L. Raston; Jerry L. Atwood

doi:10.1039/b712621b

Calix[5]arene: A versatile sublimate that displays gas sorption properties

Scott J. Dalgarno, Jian Tian, John E. Warren, Thomas E. Clark, Mohamed Makha, Colin L. Raston, Jerry L. Atwood

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Varied temperature sublimation of calix[5]arene results in the formation of two distinctly different crystal structures or polymorphs α and β, the latter of which is based on both 'self-included' and 'back-to-back' helical arrangements of the molecule, while also being active towards CO₂ sorption at room temperature and 1 atmosphere pressure.

Original language	English
Pages (from-to)	4848-4850
Number of pages	3
Journal	Chemical Communications
Issue number	46
DOIs	https://doi.org/10.1039/b712621b
Publication status	Published - 1 Dec 2007
Externally published	Yes

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10.1039/b712621b

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AU - Clark, Thomas E.

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AU - Raston, Colin L.

AU - Atwood, Jerry L.

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AB - Varied temperature sublimation of calix[5]arene results in the formation of two distinctly different crystal structures or polymorphs α and β, the latter of which is based on both 'self-included' and 'back-to-back' helical arrangements of the molecule, while also being active towards CO2 sorption at room temperature and 1 atmosphere pressure.

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Calix[5]arene: A versatile sublimate that displays gas sorption properties

Abstract

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