Carbene and radical pathways in pyrolysis of benzisoxazolones and benzotriazoles

Rolf H Prager; Mehdi M Baradarani; Jabbar Khalafy

doi:10.1002/jhet.5570370320

Carbene and radical pathways in pyrolysis of benzisoxazolones and benzotriazoles

Rolf H Prager, Mehdi M Baradarani, Jabbar Khalafy

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9 Citations (Scopus)

Abstract

A comparative study of the flash vacuum pyrolysis of a number of N-alkyl and N-acyl benzotriazoles and benzisoxazolones has confirmed that carbene derived pathways predominate at lower temperatures, and radical pathways at highter temperatures. Two new general unimolecular thermal reactions are also highlighted.

Original language	English
Pages (from-to)	631-637
Number of pages	7
Journal	Journal of Heterocyclic Chemistry
Volume	37
Issue number	3
DOIs	https://doi.org/10.1002/jhet.5570370320
Publication status	Published - May 2000

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title = "Carbene and radical pathways in pyrolysis of benzisoxazolones and benzotriazoles",

abstract = "A comparative study of the flash vacuum pyrolysis of a number of N-alkyl and N-acyl benzotriazoles and benzisoxazolones has confirmed that carbene derived pathways predominate at lower temperatures, and radical pathways at highter temperatures. Two new general unimolecular thermal reactions are also highlighted.",

author = "Prager, {Rolf H} and Baradarani, {Mehdi M} and Jabbar Khalafy",

year = "2000",

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T1 - Carbene and radical pathways in pyrolysis of benzisoxazolones and benzotriazoles

AU - Prager, Rolf H

AU - Baradarani, Mehdi M

AU - Khalafy, Jabbar

PY - 2000/5

Y1 - 2000/5

N2 - A comparative study of the flash vacuum pyrolysis of a number of N-alkyl and N-acyl benzotriazoles and benzisoxazolones has confirmed that carbene derived pathways predominate at lower temperatures, and radical pathways at highter temperatures. Two new general unimolecular thermal reactions are also highlighted.

AB - A comparative study of the flash vacuum pyrolysis of a number of N-alkyl and N-acyl benzotriazoles and benzisoxazolones has confirmed that carbene derived pathways predominate at lower temperatures, and radical pathways at highter temperatures. Two new general unimolecular thermal reactions are also highlighted.

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U2 - 10.1002/jhet.5570370320

DO - 10.1002/jhet.5570370320

M3 - Article

AN - SCOPUS:0033914662

SN - 0022-152X

VL - 37

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EP - 637

JO - Journal of Heterocyclic Chemistry

JF - Journal of Heterocyclic Chemistry

IS - 3

ER -

Carbene and radical pathways in pyrolysis of benzisoxazolones and benzotriazoles

Abstract

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