Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex

Philip C. Andrews; Peter J. Nichols; Colin L. Raston; Brett A. Roberts

doi:10.1021/om990542t

Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex

Philip C. Andrews, Peter J. Nichols, Colin L. Raston, Brett A. Roberts

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Summary: The stiba-alkene nature of the red oil produced from the 2:1 reaction of [2-Pyr(SiMe₃)₂CLi·tmeda] (Pyr = C₅H₄N) with SbCl₃ has been confirmed by mass spectrometry. The low-temperature addition of Et₃In to a hexane solution of the stiba-alkene, [2-Pyr(SiMe₃)₂CSb-C(SiMe₃)₂-Pyr], results in the first structurally authenticated In(III) /Sb(III) carbon-centered geminal organodimetallic complex, via carbometalation at the Sb=C double bond.

Original language	English
Pages (from-to)	4247-4249
Number of pages	3
Journal	Organometallics
Volume	18
Issue number	21
DOIs	https://doi.org/10.1021/om990542t
Publication status	Published - 11 Oct 1999
Externally published	Yes

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title = "Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex",

abstract = "Summary: The stiba-alkene nature of the red oil produced from the 2:1 reaction of [2-Pyr(SiMe3)2CLi·tmeda] (Pyr = C5H4N) with SbCl3 has been confirmed by mass spectrometry. The low-temperature addition of Et3In to a hexane solution of the stiba-alkene, [2-Pyr(SiMe3)2CSb-C(SiMe3)2-Pyr], results in the first structurally authenticated In(III) /Sb(III) carbon-centered geminal organodimetallic complex, via carbometalation at the Sb=C double bond.",

author = "Andrews, {Philip C.} and Nichols, {Peter J.} and Raston, {Colin L.} and Roberts, {Brett A.}",

year = "1999",

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doi = "10.1021/om990542t",

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journal = "Organometallics",

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T1 - Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex

AU - Andrews, Philip C.

AU - Nichols, Peter J.

AU - Raston, Colin L.

AU - Roberts, Brett A.

PY - 1999/10/11

Y1 - 1999/10/11

N2 - Summary: The stiba-alkene nature of the red oil produced from the 2:1 reaction of [2-Pyr(SiMe3)2CLi·tmeda] (Pyr = C5H4N) with SbCl3 has been confirmed by mass spectrometry. The low-temperature addition of Et3In to a hexane solution of the stiba-alkene, [2-Pyr(SiMe3)2CSb-C(SiMe3)2-Pyr], results in the first structurally authenticated In(III) /Sb(III) carbon-centered geminal organodimetallic complex, via carbometalation at the Sb=C double bond.

AB - Summary: The stiba-alkene nature of the red oil produced from the 2:1 reaction of [2-Pyr(SiMe3)2CLi·tmeda] (Pyr = C5H4N) with SbCl3 has been confirmed by mass spectrometry. The low-temperature addition of Et3In to a hexane solution of the stiba-alkene, [2-Pyr(SiMe3)2CSb-C(SiMe3)2-Pyr], results in the first structurally authenticated In(III) /Sb(III) carbon-centered geminal organodimetallic complex, via carbometalation at the Sb=C double bond.

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U2 - 10.1021/om990542t

DO - 10.1021/om990542t

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SN - 0276-7333

VL - 18

SP - 4247

EP - 4249

JO - Organometallics

JF - Organometallics

IS - 21

ER -

Carbometalation of a Stiba-alkene Resulting in an In(III)/Sb(III) C-Centered Geminal Organodimetallic Complex

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