Chemical constituents of the flindersia. XXIII Determination of the structure of flindercarpin-2: as methyl (s)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα,- 7α, 10aα, 11aα)]-5′, 6'-diacetoxy-7′-(furan-3″-yl)- 2′, 2′, 3a′, 6a′, 11a′-pentamethyl-12′-methylene- 9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, lla′-decahydro- 7′ H-4′, 10a′-methano-10a′ H-furo[2, 3-b]pyrano- [3, 4-g]oxocin-3′-yl) acetate

Geoffrey W. Breen; Kelvin Picker; Colin L. Raston; Brian W. Skelton; Walter C. Taylor; Allan H. White

doi:10.1071/CH9841461

Chemical constituents of the flindersia. XXIII Determination of the structure of flindercarpin-2: as methyl (s)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα,- 7α, 10aα, 11aα)]-5′, 6'-diacetoxy-7′-(furan-3″-yl)- 2′, 2′, 3a′, 6a′, 11a′-pentamethyl-12′-methylene- 9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, lla′-decahydro- 7′ H-4′, 10a′-methano-10a′ H-furo[2, 3-b]pyrano- [3, 4-g]oxocin-3′-yl) acetate

Geoffrey W. Breen, Kelvin Picker, Colin L. Raston, Brian W. Skelton, Walter C. Taylor, Allan H. White

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

Flindercarpin-2, C₃2H₄₀O₁₃, isolated from the bark of Flindersia laevicarpa C.T. White & Francis (Rutaceae) was shown by spectroscopic and crystallographic studies to be a pentanortriterpenoid, methyl (S)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα, 7α, 10aα, 11aα)]-5′, 6′-diacetoxy-7'-(furan-3″-yl)-2′, 2′- 3a′, 6a′, 11a′-pentamethyI-12'-methylene-9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, 11a′-decahydro-7′H-4′, 10a′- methano-10a′H-furo[2, 3-b]pyrano[3, 4-g]oxocin-3′-yl)acetate (2).

Original language	English
Pages (from-to)	1461-1471
Number of pages	11
Journal	Australian Journal of Chemistry
Volume	37
Issue number	7
DOIs	https://doi.org/10.1071/CH9841461
Publication status	Published - 1984
Externally published	Yes

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Breen, G. W., Picker, K., Raston, C. L., Skelton, B. W., Taylor, W. C., & White, A. H. (1984). Chemical constituents of the flindersia. XXIII Determination of the structure of flindercarpin-2: as methyl (s)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα,- 7α, 10aα, 11aα)]-5′, 6'-diacetoxy-7′-(furan-3″-yl)- 2′, 2′, 3a′, 6a′, 11a′-pentamethyl-12′-methylene- 9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, lla′-decahydro- 7′ H-4′, 10a′-methano-10a′ H-furo[2, 3-b]pyrano- [3, 4-g]oxocin-3′-yl) acetate. Australian Journal of Chemistry, 37(7), 1461-1471. https://doi.org/10.1071/CH9841461

Breen, Geoffrey W. ; Picker, Kelvin ; Raston, Colin L. et al. / Chemical constituents of the flindersia. XXIII Determination of the structure of flindercarpin-2 : as methyl (s)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα,- 7α, 10aα, 11aα)]-5′, 6'-diacetoxy-7′-(furan-3″-yl)- 2′, 2′, 3a′, 6a′, 11a′-pentamethyl-12′-methylene- 9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, lla′-decahydro- 7′ H-4′, 10a′-methano-10a′ H-furo[2, 3-b]pyrano- [3, 4-g]oxocin-3′-yl) acetate. In: Australian Journal of Chemistry. 1984 ; Vol. 37, No. 7. pp. 1461-1471.

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title = "Chemical constituents of the flindersia. XXIII Determination of the structure of flindercarpin-2: as methyl (s)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα,- 7α, 10aα, 11aα)]-5′, 6'-diacetoxy-7′-(furan-3″-yl)- 2′, 2′, 3a′, 6a′, 11a′-pentamethyl-12′-methylene- 9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, lla′-decahydro- 7′ H-4′, 10a′-methano-10a′ H-furo[2, 3-b]pyrano- [3, 4-g]oxocin-3′-yl) acetate",

abstract = "Flindercarpin-2, C32H40O13, isolated from the bark of Flindersia laevicarpa C.T. White & Francis (Rutaceae) was shown by spectroscopic and crystallographic studies to be a pentanortriterpenoid, methyl (S)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα, 7α, 10aα, 11aα)]-5′, 6′-diacetoxy-7'-(furan-3″-yl)-2′, 2′- 3a′, 6a′, 11a′-pentamethyI-12'-methylene-9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, 11a′-decahydro-7′H-4′, 10a′- methano-10a′H-furo[2, 3-b]pyrano[3, 4-g]oxocin-3′-yl)acetate (2).",

author = "Breen, {Geoffrey W.} and Kelvin Picker and Raston, {Colin L.} and Skelton, {Brian W.} and Taylor, {Walter C.} and White, {Allan H.}",

year = "1984",

doi = "10.1071/CH9841461",

language = "English",

volume = "37",

pages = "1461--1471",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO Publishing",

number = "7",

}

Breen, GW, Picker, K, Raston, CL, Skelton, BW, Taylor, WC & White, AH 1984, 'Chemical constituents of the flindersia. XXIII Determination of the structure of flindercarpin-2: as methyl (s)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα,- 7α, 10aα, 11aα)]-5′, 6'-diacetoxy-7′-(furan-3″-yl)- 2′, 2′, 3a′, 6a′, 11a′-pentamethyl-12′-methylene- 9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, lla′-decahydro- 7′ H-4′, 10a′-methano-10a′ H-furo[2, 3-b]pyrano- [3, 4-g]oxocin-3′-yl) acetate', Australian Journal of Chemistry, vol. 37, no. 7, pp. 1461-1471. https://doi.org/10.1071/CH9841461

Chemical constituents of the flindersia. XXIII Determination of the structure of flindercarpin-2: as methyl (s)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα,- 7α, 10aα, 11aα)]-5′, 6'-diacetoxy-7′-(furan-3″-yl)- 2′, 2′, 3a′, 6a′, 11a′-pentamethyl-12′-methylene- 9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, lla′-decahydro- 7′ H-4′, 10a′-methano-10a′ H-furo[2, 3-b]pyrano- [3, 4-g]oxocin-3′-yl) acetate. / Breen, Geoffrey W.; Picker, Kelvin; Raston, Colin L. et al.
In: Australian Journal of Chemistry, Vol. 37, No. 7, 1984, p. 1461-1471.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Chemical constituents of the flindersia. XXIII Determination of the structure of flindercarpin-2

T2 - as methyl (s)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα,- 7α, 10aα, 11aα)]-5′, 6'-diacetoxy-7′-(furan-3″-yl)- 2′, 2′, 3a′, 6a′, 11a′-pentamethyl-12′-methylene- 9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, lla′-decahydro- 7′ H-4′, 10a′-methano-10a′ H-furo[2, 3-b]pyrano- [3, 4-g]oxocin-3′-yl) acetate

AU - Breen, Geoffrey W.

AU - Picker, Kelvin

AU - Raston, Colin L.

AU - Skelton, Brian W.

AU - Taylor, Walter C.

AU - White, Allan H.

PY - 1984

Y1 - 1984

N2 - Flindercarpin-2, C32H40O13, isolated from the bark of Flindersia laevicarpa C.T. White & Francis (Rutaceae) was shown by spectroscopic and crystallographic studies to be a pentanortriterpenoid, methyl (S)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα, 7α, 10aα, 11aα)]-5′, 6′-diacetoxy-7'-(furan-3″-yl)-2′, 2′- 3a′, 6a′, 11a′-pentamethyI-12'-methylene-9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, 11a′-decahydro-7′H-4′, 10a′- methano-10a′H-furo[2, 3-b]pyrano[3, 4-g]oxocin-3′-yl)acetate (2).

AB - Flindercarpin-2, C32H40O13, isolated from the bark of Flindersia laevicarpa C.T. White & Francis (Rutaceae) was shown by spectroscopic and crystallographic studies to be a pentanortriterpenoid, methyl (S)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα, 7α, 10aα, 11aα)]-5′, 6′-diacetoxy-7'-(furan-3″-yl)-2′, 2′- 3a′, 6a′, 11a′-pentamethyI-12'-methylene-9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, 11a′-decahydro-7′H-4′, 10a′- methano-10a′H-furo[2, 3-b]pyrano[3, 4-g]oxocin-3′-yl)acetate (2).

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U2 - 10.1071/CH9841461

DO - 10.1071/CH9841461

M3 - Article

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SN - 0004-9425

VL - 37

SP - 1461

EP - 1471

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 7

ER -

Breen GW, Picker K, Raston CL, Skelton BW, Taylor WC, White AH. Chemical constituents of the flindersia. XXIII Determination of the structure of flindercarpin-2: as methyl (s)-(acetoxy)([3′S-(3α, 3aα, 4α, 5β, 6α, 6aα,- 7α, 10aα, 11aα)]-5′, 6'-diacetoxy-7′-(furan-3″-yl)- 2′, 2′, 3a′, 6a′, 11a′-pentamethyl-12′-methylene- 9′-oxo-2′, 3′, 3a′, 4′, 5′, 6′, 6a′, 9′, 10′, lla′-decahydro- 7′ H-4′, 10a′-methano-10a′ H-furo[2, 3-b]pyrano- [3, 4-g]oxocin-3′-yl) acetate. Australian Journal of Chemistry. 1984;37(7):1461-1471. doi: 10.1071/CH9841461

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