Comparison of singlet methylene removal rates by group IV hydrides

Greg J. Gutsche; Warren D. Lawrance; Warren S. Staker; Keith D. King

doi:10.1002/kin.550270612

Comparison of singlet methylene removal rates by group IV hydrides

Greg J. Gutsche, Warren D. Lawrance, Warren S. Staker, Keith D. King

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Abstract

The technique of laser flash photolysis/laser absorption has been used to obtain an absolute removal rate constant of (3.85 ± 0.18) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ for singlet methylene, ¹CH₂ (ã¹A₁), with germane (GeH₄) at ambient temperature. The removal rate constant is compared with the values for methane (CH₄) and silane (SiH₄) which have been determined previously.

Original language	English
Pages (from-to)	623-626
Number of pages	4
Journal	International Journal of Chemical Kinetics
Volume	27
Issue number	6
DOIs	https://doi.org/10.1002/kin.550270612
Publication status	Published - 1 Jun 1995

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abstract = "The technique of laser flash photolysis/laser absorption has been used to obtain an absolute removal rate constant of (3.85 ± 0.18) × 10−10 cm3 molecule−1 s−1 for singlet methylene, 1CH2 ({\~a}1A1), with germane (GeH4) at ambient temperature. The removal rate constant is compared with the values for methane (CH4) and silane (SiH4) which have been determined previously.",

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AU - Staker, Warren S.

AU - King, Keith D.

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AB - The technique of laser flash photolysis/laser absorption has been used to obtain an absolute removal rate constant of (3.85 ± 0.18) × 10−10 cm3 molecule−1 s−1 for singlet methylene, 1CH2 (ã1A1), with germane (GeH4) at ambient temperature. The removal rate constant is compared with the values for methane (CH4) and silane (SiH4) which have been determined previously.

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Comparison of singlet methylene removal rates by group IV hydrides

Abstract

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