TY - JOUR
T1 - Computational Study on the Adsorption of Sodium and Calcium on Edge-Functionalized Graphene Nanoribbons
AU - Farokh Niaei, Amir H.
AU - Roman, Tanglaw
AU - Hussain, Tanveer
AU - Searles, Debra J.
PY - 2019/6/20
Y1 - 2019/6/20
N2 - Computational methods are used to show that graphene nanoribbons bind sodium (Na) and calcium (Ca) more strongly than graphene sheets. The binding strength is further enhanced by functionalizing the edge of the nanoribbon with oxygen-containing groups. Strengthening of the binding of these metal atoms to graphitic materials is important for applications including metal-ion batteries. Our results are obtained using density functional theory calculations of the binding of sodium and calcium to hydrogen, hydroxyl, carbonyl, and carboxyl groups at the edge of zigzag and armchair nanoribbons. Both hydrogen passivation and hydroxyl functionalization result in moderate binding of Na and Ca with binding energies varying from -1.0 to -1.9 eV for the nanoribbons considered. An increase in binding compared to graphene does not just occur at the edge, but extends across the nanoribbon. Furthermore, carbonyl and carboxyl groups bound both metal atoms more strongly, with binding energies between -1.6 and -3.1 eV. Increasing the number of these groups at the edge increases the binding strength of the metal adatoms. When there is a high number of oxygen-containing groups at the edge, the effect of the oxygen-containing groups is also evident away from the edge of the nanoribbon for sodium and calcium. It is demonstrated that this is at least partly due to the change in the electronic structure spanning the entire width of the nanoribbons considered.
AB - Computational methods are used to show that graphene nanoribbons bind sodium (Na) and calcium (Ca) more strongly than graphene sheets. The binding strength is further enhanced by functionalizing the edge of the nanoribbon with oxygen-containing groups. Strengthening of the binding of these metal atoms to graphitic materials is important for applications including metal-ion batteries. Our results are obtained using density functional theory calculations of the binding of sodium and calcium to hydrogen, hydroxyl, carbonyl, and carboxyl groups at the edge of zigzag and armchair nanoribbons. Both hydrogen passivation and hydroxyl functionalization result in moderate binding of Na and Ca with binding energies varying from -1.0 to -1.9 eV for the nanoribbons considered. An increase in binding compared to graphene does not just occur at the edge, but extends across the nanoribbon. Furthermore, carbonyl and carboxyl groups bound both metal atoms more strongly, with binding energies between -1.6 and -3.1 eV. Increasing the number of these groups at the edge increases the binding strength of the metal adatoms. When there is a high number of oxygen-containing groups at the edge, the effect of the oxygen-containing groups is also evident away from the edge of the nanoribbon for sodium and calcium. It is demonstrated that this is at least partly due to the change in the electronic structure spanning the entire width of the nanoribbons considered.
KW - Binding energy
KW - Metals
KW - Adsorption
KW - Two dimensional materials
KW - Functional groups
UR - http://www.scopus.com/inward/record.url?scp=85067379370&partnerID=8YFLogxK
UR - http://purl.org/au-research/grants/ARC/LE0882357
UR - http://purl.org/au-research/grants/ARC/LE160100051
UR - http://purl.org/au-research/grants/ARC/DP140100193
U2 - 10.1021/acs.jpcc.9b02003
DO - 10.1021/acs.jpcc.9b02003
M3 - Article
AN - SCOPUS:85067379370
VL - 123
SP - 14895
EP - 14908
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 24
ER -