Confinement of [(H2O)2 intersection set ([18]Crown-6)] in a disc- shaped cavity lined with six nickel(II) macrocycle dimers acting as divergent receptor molecules

Colin L. Raston; Peter J. Nichols; Krisztian Baranyai

doi:10.1002/(SICI)1521-3773(20000515)39:10<1842::AID-ANIE1842>3.0.CO;2-7

Confinement of [(H₂O)₂ intersection set ([18]Crown-6)] in a disc- shaped cavity lined with six nickel(II) macrocycle dimers acting as divergent receptor molecules

Colin L. Raston, Peter J. Nichols, Krisztian Baranyai

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Fifteen components build a supermolecule, comprised of two water molecules binding [18]crown-6 and this is itself enclosed by six saddle- shaped [Ni(tmtaa)]₂ macrocycles (see picture). The supermolecule interlocks into a two-dimensional layer. An analogous, metal-free supermolecule affords a layered structure consisting of (H₂TMTAA)₂ dimers separated by layers of [18]crown-6.

Original language	English
Pages (from-to)	1842-1845
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	10
DOIs	https://doi.org/10.1002/(SICI)1521-3773(20000515)39:10<1842::AID-ANIE1842>3.0.CO;2-7
Publication status	Published - 15 May 2000
Externally published	Yes

Keywords

Crown compounds
Macrocycles
Nanostructures
Self assembly
Supramolecular chemistry

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10.1002/(SICI)1521-3773(20000515)39:10<1842::AID-ANIE1842>3.0.CO;2-7Licence: In Copyright

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title = "Confinement of [(H2O)2 intersection set ([18]Crown-6)] in a disc- shaped cavity lined with six nickel(II) macrocycle dimers acting as divergent receptor molecules",

abstract = "Fifteen components build a supermolecule, comprised of two water molecules binding [18]crown-6 and this is itself enclosed by six saddle- shaped [Ni(tmtaa)]2 macrocycles (see picture). The supermolecule interlocks into a two-dimensional layer. An analogous, metal-free supermolecule affords a layered structure consisting of (H2TMTAA)2 dimers separated by layers of [18]crown-6.",

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Confinement of [(H₂O)₂ intersection set ([18]Crown-6)] in a disc- shaped cavity lined with six nickel(II) macrocycle dimers acting as divergent receptor molecules. / Raston, Colin L.; Nichols, Peter J.; Baranyai, Krisztian.
In: Angewandte Chemie - International Edition, Vol. 39, No. 10, 15.05.2000, p. 1842-1845.

Research output: Contribution to journal › Article › peer-review

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T1 - Confinement of [(H2O)2 intersection set ([18]Crown-6)] in a disc- shaped cavity lined with six nickel(II) macrocycle dimers acting as divergent receptor molecules

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AU - Baranyai, Krisztian

PY - 2000/5/15

Y1 - 2000/5/15

N2 - Fifteen components build a supermolecule, comprised of two water molecules binding [18]crown-6 and this is itself enclosed by six saddle- shaped [Ni(tmtaa)]2 macrocycles (see picture). The supermolecule interlocks into a two-dimensional layer. An analogous, metal-free supermolecule affords a layered structure consisting of (H2TMTAA)2 dimers separated by layers of [18]crown-6.

AB - Fifteen components build a supermolecule, comprised of two water molecules binding [18]crown-6 and this is itself enclosed by six saddle- shaped [Ni(tmtaa)]2 macrocycles (see picture). The supermolecule interlocks into a two-dimensional layer. An analogous, metal-free supermolecule affords a layered structure consisting of (H2TMTAA)2 dimers separated by layers of [18]crown-6.

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KW - Macrocycles

KW - Nanostructures

KW - Self assembly

KW - Supramolecular chemistry

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Confinement of [(H₂O)₂ intersection set ([18]Crown-6)] in a disc- shaped cavity lined with six nickel(II) macrocycle dimers acting as divergent receptor molecules

Abstract

Keywords

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