Confinement of (S)-serine in tetra-p-sulfonatocalix[4]arene bilayers

Peter J. Nichols; Colin L. Raston

doi:10.1039/b301316b

Confinement of (S)-serine in tetra-p-sulfonatocalix[4]arene bilayers

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Abstract

Supramolecular complexes of tetra-p-sulfonatocalix[4]arene and (S)-serine have been isolated in the solid state and their molecular structures elucidated by X-ray diffraction studies. Chiral pairs of (S)-serine molecules are confined in ‘capsules’ of tetra-p-sulfonatocalix[4]arene in an overall bilayer arrangement. Complexes containing differing amounts of sodium and caesium cations are reported.

Original language	English
Pages (from-to)	2923-2927
Number of pages	5
Journal	Journal of the Chemical Society. Dalton Transactions
Volume	3
Issue number	14
DOIs	https://doi.org/10.1039/b301316b
Publication status	Published - 12 Jun 2003
Externally published	Yes

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abstract = "Supramolecular complexes of tetra-p-sulfonatocalix[4]arene and (S)-serine have been isolated in the solid state and their molecular structures elucidated by X-ray diffraction studies. Chiral pairs of (S)-serine molecules are confined in {\textquoteleft}capsules{\textquoteright} of tetra-p-sulfonatocalix[4]arene in an overall bilayer arrangement. Complexes containing differing amounts of sodium and caesium cations are reported.",

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year = "2003",

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AU - Raston, Colin L.

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N2 - Supramolecular complexes of tetra-p-sulfonatocalix[4]arene and (S)-serine have been isolated in the solid state and their molecular structures elucidated by X-ray diffraction studies. Chiral pairs of (S)-serine molecules are confined in ‘capsules’ of tetra-p-sulfonatocalix[4]arene in an overall bilayer arrangement. Complexes containing differing amounts of sodium and caesium cations are reported.

AB - Supramolecular complexes of tetra-p-sulfonatocalix[4]arene and (S)-serine have been isolated in the solid state and their molecular structures elucidated by X-ray diffraction studies. Chiral pairs of (S)-serine molecules are confined in ‘capsules’ of tetra-p-sulfonatocalix[4]arene in an overall bilayer arrangement. Complexes containing differing amounts of sodium and caesium cations are reported.

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Confinement of (S)-serine in tetra-p-sulfonatocalix[4]arene bilayers

Abstract

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