Continuous flow fabrication of green graphene oxide in aqueous hydrogen peroxide

Kasturi Vimalanathan, James Scott, Xun Pan, Xuan Luo, Soraya Rahpeima, Qiang Sun, Jin Zou, Nidhi Bansal, Elisabeth Prabawati, Wei Zhang, Nadim Darwish, Mats R. Andersson, Qin Li, Colin L. Raston

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)
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Abstract

Highly processible graphene oxide (GO) has a diversity of applications as a material readily dispersed in aqueous media. However, methods for preparing such free-standing GO use hazardous and toxic reagents and generate significant waste streams. This is an impediment for uptake of GO in any application, for developing sustainable technologies and industries, and overcoming this remains a major challenge. We have developed a robust scalable continuous flow method for fabricating GO directly from graphite in 30% aqueous hydrogen peroxide which dramatically minimises the generation of waste. The process features the continuous flow thin film microfluidic vortex fluidic device (VFD), operating at specific conditions while irradiated sequentially by UV LED than a NIR pulsed laser. The resulting ‘green’ graphene oxide (gGO) has unique properties, possessing highly oxidized edges with large intact sp2 domains which gives rise to exceptional electrical and optical properties, including purple to deep blue emission of narrow full width at half maximum (<35 nm). Colloidally stable gGO exhibits cytotoxicity owing to the oxidised surface groups while solid-state films of gGO are biocompatible. The continuous flow method of generating gGO also provides unprecedented control of the level of oxidation and its location in the exfoliated graphene sheets by harnessing the high shear topological fluid flows in the liquid, and varying the wavelength, power and pulse frequency of the light source.

Original languageEnglish
Pages (from-to)3121-3130
Number of pages10
JournalNanoscale Advances
Volume4
Issue number15
Early online date19 May 2022
DOIs
Publication statusPublished - 7 Aug 2022

Keywords

  • graphene oxide (GO)
  • ‘green’ graphene oxide (gGO)
  • Nanoscale

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