TY - JOUR
T1 - Coupled reactive flow and dissolution with changing reactive surface and porosity
AU - Altree-Williams, A.
AU - Brugger, J.
AU - Pring, A.
AU - Bedrikovetsky, P.
PY - 2019/10/12
Y1 - 2019/10/12
N2 - Mineral dissolution flows in porous media occur in numerous industrial and natural processes. We investigate the effects of varying rock-liquid interface on mineral dissolution transport in porous media. The one-dimensional mineral-dissolution flow problem that accounts for varying reacting interface and porosity is essentially non-linear. However, a novel exact solution is derived. The exact solution reveals a four-zone structure of the flow pattern with typical mineral concentration curves in all zones. The exact solution allows for a simplified inverse solver, facilitating determination of the surface function from laboratory reactive flow tests. Accounting for surface area evolution in the governing system of equations allows for significant improvement of matching the experimental data if compared with the constant-surface model. Moreover, the comparison between the analytical model and laboratory data reveals high agreement. The values of equilibrium mineral concentration as obtained from the matching and by thermodynamic calculations exhibit close agreement.
AB - Mineral dissolution flows in porous media occur in numerous industrial and natural processes. We investigate the effects of varying rock-liquid interface on mineral dissolution transport in porous media. The one-dimensional mineral-dissolution flow problem that accounts for varying reacting interface and porosity is essentially non-linear. However, a novel exact solution is derived. The exact solution reveals a four-zone structure of the flow pattern with typical mineral concentration curves in all zones. The exact solution allows for a simplified inverse solver, facilitating determination of the surface function from laboratory reactive flow tests. Accounting for surface area evolution in the governing system of equations allows for significant improvement of matching the experimental data if compared with the constant-surface model. Moreover, the comparison between the analytical model and laboratory data reveals high agreement. The values of equilibrium mineral concentration as obtained from the matching and by thermodynamic calculations exhibit close agreement.
KW - Exact solution
KW - Mathematical model
KW - Mineral dissolution
KW - Porous media
KW - Reactive flow
KW - Reactive surface
UR - http://www.scopus.com/inward/record.url?scp=85066107785&partnerID=8YFLogxK
UR - http://purl.org/au-research/grants/ARC/DP140102765
UR - http://purl.org/au-research/grants/ARC/LP150100626
UR - http://purl.org/au-research/grants/ARC/LP160101497
U2 - 10.1016/j.ces.2019.05.016
DO - 10.1016/j.ces.2019.05.016
M3 - Article
AN - SCOPUS:85066107785
VL - 206
SP - 289
EP - 304
JO - Chemical Engineering Science
JF - Chemical Engineering Science
SN - 0009-2509
ER -