TY - JOUR
T1 - Crystal structure of µ-pyrazine-bis(penta-ammineruthenium) penta-(bromide chloride)–water (1/4)
AU - Beattie, James K.
AU - Hush, Noel S.
AU - Taylor, Peter R.
AU - Raston, Colin L.
AU - White, Allan H.
PY - 1977
Y1 - 1977
N2 - The crystal structure of the title compound, [(NH3)5Ru·N(CH)4N·Ru(NH 3)5] Br10/3Cl5/3·4H2O, has been determined from X-ray diffractometer data by direct methods and refined by full-matrix least squares to R 0.062 for 2 951 observed reflections. Crystals are orthorhombic, probable space group Pnnm, a = 17.790(4), b = 11.590(2), c = 7.096(1) Å, Z = 2. The cation has exact crystallographic symmetry of at least 2, and approximate mmm symmetry; Ru-N(pyrazine) is 2.006(6), Ru-NH3(trans) 2.127(7), and Ru-NH3(cis) 2.098(5) and 2.122(5) Å. The anions, together with the water molecules, are highly disordered.
AB - The crystal structure of the title compound, [(NH3)5Ru·N(CH)4N·Ru(NH 3)5] Br10/3Cl5/3·4H2O, has been determined from X-ray diffractometer data by direct methods and refined by full-matrix least squares to R 0.062 for 2 951 observed reflections. Crystals are orthorhombic, probable space group Pnnm, a = 17.790(4), b = 11.590(2), c = 7.096(1) Å, Z = 2. The cation has exact crystallographic symmetry of at least 2, and approximate mmm symmetry; Ru-N(pyrazine) is 2.006(6), Ru-NH3(trans) 2.127(7), and Ru-NH3(cis) 2.098(5) and 2.122(5) Å. The anions, together with the water molecules, are highly disordered.
UR - http://www.scopus.com/inward/record.url?scp=37049098680&partnerID=8YFLogxK
U2 - 10.1039/DT9770001121
DO - 10.1039/DT9770001121
M3 - Article
AN - SCOPUS:37049098680
SP - 1121
EP - 1124
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
SN - 1470-479X
IS - 11
ER -