Crystal structure of 2, 4-Di-t-butyl-6-(3, 5-di-t-butyl-2-hydroxyphenyl)-6-morpholinocyclohexa-2, 4-dienone

Sydney R. Hall; David G. Hewitt; Colin L. Raston; Allan H. White

doi:10.1071/CH9782721

Crystal structure of 2, 4-Di-t-butyl-6-(3, 5-di-t-butyl-2-hydroxyphenyl)-6-morpholinocyclohexa-2, 4-dienone

Sydney R. Hall, David G. Hewitt, Colin L. Raston, Allan H. White

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal structure of the title compound, C32H49NO3, has been determined by single-crystal X-ray diffraction at 295(1) K and refined by least squares to a residual of 0·061 for 1721 ‘observed’ reflections. Crystals are orthorhombic, P cab, a 18·63(2), b 18·58(2), c 18·19(2) Å, Z8. The structure determination confirms that proposed on chemical grounds and shows an unusual t-butyl n.m.r. chemical shift to be a consequence of an unusual orientation.

Original language	English
Pages (from-to)	2721-2725
Number of pages	5
Journal	Australian Journal of Chemistry
Volume	31
Issue number	12
DOIs	https://doi.org/10.1071/CH9782721
Publication status	Published - 1978
Externally published	Yes

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title = "Crystal structure of 2, 4-Di-t-butyl-6-(3, 5-di-t-butyl-2-hydroxyphenyl)-6-morpholinocyclohexa-2, 4-dienone",

abstract = "The crystal structure of the title compound, C32H49NO3, has been determined by single-crystal X-ray diffraction at 295(1) K and refined by least squares to a residual of 0·061 for 1721 {\textquoteleft}observed{\textquoteright} reflections. Crystals are orthorhombic, P cab, a 18·63(2), b 18·58(2), c 18·19(2) {\AA}, Z8. The structure determination confirms that proposed on chemical grounds and shows an unusual t-butyl n.m.r. chemical shift to be a consequence of an unusual orientation.",

author = "Hall, {Sydney R.} and Hewitt, {David G.} and Raston, {Colin L.} and White, {Allan H.}",

year = "1978",

doi = "10.1071/CH9782721",

language = "English",

volume = "31",

pages = "2721--2725",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

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T1 - Crystal structure of 2, 4-Di-t-butyl-6-(3, 5-di-t-butyl-2-hydroxyphenyl)-6-morpholinocyclohexa-2, 4-dienone

AU - Hall, Sydney R.

AU - Hewitt, David G.

AU - Raston, Colin L.

AU - White, Allan H.

PY - 1978

Y1 - 1978

N2 - The crystal structure of the title compound, C32H49NO3, has been determined by single-crystal X-ray diffraction at 295(1) K and refined by least squares to a residual of 0·061 for 1721 ‘observed’ reflections. Crystals are orthorhombic, P cab, a 18·63(2), b 18·58(2), c 18·19(2) Å, Z8. The structure determination confirms that proposed on chemical grounds and shows an unusual t-butyl n.m.r. chemical shift to be a consequence of an unusual orientation.

AB - The crystal structure of the title compound, C32H49NO3, has been determined by single-crystal X-ray diffraction at 295(1) K and refined by least squares to a residual of 0·061 for 1721 ‘observed’ reflections. Crystals are orthorhombic, P cab, a 18·63(2), b 18·58(2), c 18·19(2) Å, Z8. The structure determination confirms that proposed on chemical grounds and shows an unusual t-butyl n.m.r. chemical shift to be a consequence of an unusual orientation.

UR - http://www.scopus.com/inward/record.url?scp=84970581177&partnerID=8YFLogxK

U2 - 10.1071/CH9782721

DO - 10.1071/CH9782721

M3 - Article

AN - SCOPUS:84970581177

SN - 0004-9425

VL - 31

SP - 2721

EP - 2725

JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 12

ER -

Crystal structure of 2, 4-Di-t-butyl-6-(3, 5-di-t-butyl-2-hydroxyphenyl)-6-morpholinocyclohexa-2, 4-dienone

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