TY - JOUR
T1 - Crystal structure of a linear polymeric 1:1 adduct of copper(I) chloride and 2,3-diazabicyclo[2,2,1]hept-2-ene
AU - Chandler, Graham S.
AU - Raston, Colin L.
AU - Walker, Geoffrey W.
AU - White, Allan H.
PY - 1974
Y1 - 1974
N2 - The crystal structure of the title compound has been determined by Patterson and Fourier methods from single-crystal photographic X-ray diffraction data, and refined by full-matrix least-squares methods to R 0.11 (401 reflections). Crystals are orthorhombic, space group Pb21m, a = 9.63(1), b = 10.64(1), c = 6.71(1) Å, Z = 4. The structure comprises a linear chain of copper atoms alternately spaced at 3.32 and 3.39(1) Å, the copper atoms being spanned by ligand and chlorine bridges; the copper environment is basically a distorted tetrahedron: Cu-Cl 2.37 and 2.38(1), Cu-N 1.88 and 1.92(2) Å; N-Cu-NI 128(1), Cl-Cu-ClI, 117(1), N-Cu-Cl, 100-106°.
AB - The crystal structure of the title compound has been determined by Patterson and Fourier methods from single-crystal photographic X-ray diffraction data, and refined by full-matrix least-squares methods to R 0.11 (401 reflections). Crystals are orthorhombic, space group Pb21m, a = 9.63(1), b = 10.64(1), c = 6.71(1) Å, Z = 4. The structure comprises a linear chain of copper atoms alternately spaced at 3.32 and 3.39(1) Å, the copper atoms being spanned by ligand and chlorine bridges; the copper environment is basically a distorted tetrahedron: Cu-Cl 2.37 and 2.38(1), Cu-N 1.88 and 1.92(2) Å; N-Cu-NI 128(1), Cl-Cu-ClI, 117(1), N-Cu-Cl, 100-106°.
UR - http://www.scopus.com/inward/record.url?scp=37049123502&partnerID=8YFLogxK
U2 - 10.1039/DT9740001797
DO - 10.1039/DT9740001797
M3 - Article
AN - SCOPUS:37049123502
SN - 1472-7773
SP - 1797
EP - 1799
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 16
ER -