The crystal structure of the title compound has been determined at 295 K by single-crystal X-ray diffraction and refined by least squares to a residual of 0·062. Crystals are monoclinic, P2/c, a 19·102(8), b 8·117(4), c 16·610(8) ì β111·90(3)°, Z 4. Unlike the tris(a-oxyimino ketonato)iron(ii) complexes which are fac, the present derivative is based upon substitution of the two picoline moieties into a mer derivative, trans to the nitrogen atoms of the chelate ligands. 〈Fe-N(picoline)〉 is 2·02 0 ; 〈Fe-N, O(chelate)〉 l·88 0 , l-95 2 î.
|Number of pages||5|
|Journal||Australian Journal of Chemistry|
|Publication status||Published - 1978|