Crystal Structure of ab-Bis(3-methylpyridine)- dc, fe-bis(pentane-2, 3, 4-trione 3-oximato)iron(II)

Brian N. Figgis, Colin L. Raston, Raj Pal Sharma, Allan H. White

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

The crystal structure of the title compound has been determined at 295 K by single-crystal X-ray diffraction and refined by least squares to a residual of 0·062. Crystals are monoclinic, P2/c, a 19·102(8), b 8·117(4), c 16·610(8) ì β111·90(3)°, Z 4. Unlike the tris(a-oxyimino ketonato)iron(ii) complexes which are fac, the present derivative is based upon substitution of the two picoline moieties into a mer derivative, trans to the nitrogen atoms of the chelate ligands. 〈Fe-N(picoline)〉 is 2·02 0 ; 〈Fe-N, O(chelate)〉 l·88 0 , l-95 2 î.

Original languageEnglish
Pages (from-to)2431-2435
Number of pages5
JournalAustralian Journal of Chemistry
Volume31
Issue number11
DOIs
Publication statusPublished - 1978
Externally publishedYes

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