Crystal Structure of ab-Bis(3-methylpyridine)- dc, fe-bis(pentane-2, 3, 4-trione 3-oximato)iron(II)

Brian N. Figgis; Colin L. Raston; Raj Pal Sharma; Allan H. White

doi:10.1071/CH9782431

Crystal Structure of ab-Bis(3-methylpyridine)- dc, fe-bis(pentane-2, 3, 4-trione 3-oximato)iron(II)

Brian N. Figgis, Colin L. Raston, Raj Pal Sharma, Allan H. White

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

The crystal structure of the title compound has been determined at 295 K by single-crystal X-ray diffraction and refined by least squares to a residual of 0·062. Crystals are monoclinic, P2/c, a 19·102(8), b 8·117(4), c 16·610(8) ì β111·90(3)°, Z 4. Unlike the tris(a-oxyimino ketonato)iron(ii) complexes which are fac, the present derivative is based upon substitution of the two picoline moieties into a mer derivative, trans to the nitrogen atoms of the chelate ligands. 〈Fe-N(picoline)〉 is 2·02 ₀ ; 〈Fe-N, O(chelate)〉 l·88 ₀ , l-95 ₂ î.

Original language	English
Pages (from-to)	2431-2435
Number of pages	5
Journal	Australian Journal of Chemistry
Volume	31
Issue number	11
DOIs	https://doi.org/10.1071/CH9782431
Publication status	Published - 1978
Externally published	Yes

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@article{143e552ab05a446db78e85a24634852f,

title = "Crystal Structure of ab-Bis(3-methylpyridine)- dc, fe-bis(pentane-2, 3, 4-trione 3-oximato)iron(II)",

abstract = " The crystal structure of the title compound has been determined at 295 K by single-crystal X-ray diffraction and refined by least squares to a residual of 0·062. Crystals are monoclinic, P2/c, a 19·102(8), b 8·117(4), c 16·610(8) {\`i} β111·90(3)°, Z 4. Unlike the tris(a-oxyimino ketonato)iron(ii) complexes which are fac, the present derivative is based upon substitution of the two picoline moieties into a mer derivative, trans to the nitrogen atoms of the chelate ligands. 〈Fe-N(picoline)〉 is 2·02 0 ; 〈Fe-N, O(chelate)〉 l·88 0 , l-95 2 {\^i}.",

author = "Figgis, {Brian N.} and Raston, {Colin L.} and Sharma, {Raj Pal} and White, {Allan H.}",

year = "1978",

doi = "10.1071/CH9782431",

language = "English",

volume = "31",

pages = "2431--2435",

journal = "Australian Journal of Chemistry",

issn = "0004-9425",

publisher = "CSIRO Publishing",

number = "11",

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TY - JOUR

T1 - Crystal Structure of ab-Bis(3-methylpyridine)- dc, fe-bis(pentane-2, 3, 4-trione 3-oximato)iron(II)

AU - Figgis, Brian N.

AU - Raston, Colin L.

AU - Sharma, Raj Pal

AU - White, Allan H.

PY - 1978

Y1 - 1978

N2 - The crystal structure of the title compound has been determined at 295 K by single-crystal X-ray diffraction and refined by least squares to a residual of 0·062. Crystals are monoclinic, P2/c, a 19·102(8), b 8·117(4), c 16·610(8) ì β111·90(3)°, Z 4. Unlike the tris(a-oxyimino ketonato)iron(ii) complexes which are fac, the present derivative is based upon substitution of the two picoline moieties into a mer derivative, trans to the nitrogen atoms of the chelate ligands. 〈Fe-N(picoline)〉 is 2·02 0 ; 〈Fe-N, O(chelate)〉 l·88 0 , l-95 2 î.

AB - The crystal structure of the title compound has been determined at 295 K by single-crystal X-ray diffraction and refined by least squares to a residual of 0·062. Crystals are monoclinic, P2/c, a 19·102(8), b 8·117(4), c 16·610(8) ì β111·90(3)°, Z 4. Unlike the tris(a-oxyimino ketonato)iron(ii) complexes which are fac, the present derivative is based upon substitution of the two picoline moieties into a mer derivative, trans to the nitrogen atoms of the chelate ligands. 〈Fe-N(picoline)〉 is 2·02 0 ; 〈Fe-N, O(chelate)〉 l·88 0 , l-95 2 î.

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U2 - 10.1071/CH9782431

DO - 10.1071/CH9782431

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JO - Australian Journal of Chemistry

JF - Australian Journal of Chemistry

IS - 11

ER -

Crystal Structure of ab-Bis(3-methylpyridine)- dc, fe-bis(pentane-2, 3, 4-trione 3-oximato)iron(II)

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