TY - JOUR
T1 - Crystal structure of aqua(2,2′:6′,2″:6″,2‴-quaterpyridyl)sulphitocobalt-(III) nitrate monohydrate
AU - Maslen, Edward N.
AU - Raston, Colin L.
AU - White, Allan H.
PY - 1975
Y1 - 1975
N2 - The crystal structure of the title compound has been determined by the heavy-atom method from X-ray diffracto-meter data and refined by block-diagonal least-squares to R 0.056 for 1891 observed reflections. Crystals are monoclinic, space group P21/n, a = 19.005(4), b = 15.598(3), c = 6.913(1) Å, β = 92.34(1)°, Z = 4. The quaterpyridyl ligand is planar and coplanar with the cobalt, the inner nitrogen atoms bonding to it at a shorter distance (1.855 ± 0.005) than the outer (1.97 ± 0.01 Å). Co-OH2 is 2.067(5) and Co-S 2.244(2) Å. The nitrate ion is disordered.
AB - The crystal structure of the title compound has been determined by the heavy-atom method from X-ray diffracto-meter data and refined by block-diagonal least-squares to R 0.056 for 1891 observed reflections. Crystals are monoclinic, space group P21/n, a = 19.005(4), b = 15.598(3), c = 6.913(1) Å, β = 92.34(1)°, Z = 4. The quaterpyridyl ligand is planar and coplanar with the cobalt, the inner nitrogen atoms bonding to it at a shorter distance (1.855 ± 0.005) than the outer (1.97 ± 0.01 Å). Co-OH2 is 2.067(5) and Co-S 2.244(2) Å. The nitrate ion is disordered.
UR - http://www.scopus.com/inward/record.url?scp=37049116067&partnerID=8YFLogxK
U2 - 10.1039/DT9750000323
DO - 10.1039/DT9750000323
M3 - Article
AN - SCOPUS:37049116067
SP - 323
EP - 326
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
SN - 1470-479X
IS - 4
ER -