TY - JOUR
T1 - Crystal structure of bis(diethyldithiocarbamato)oxovanadium(IV)
AU - Henrick, Kim
AU - Raston, Colin L.
AU - White, Allan H.
PY - 1976
Y1 - 1976
N2 - The crystal structure of the title compound, [VO(CS2·NEt2)2], has been determined by direct methods and refined by full-matrix least-squares to R 0.056 for 2 017 reflections. Crystals are monoclinic, space group P21/c, a = 12.863(4), b = 14.023(5), c = 9.558(3) Å, β = 104.05(3)°, Z = 4. The molecular core has the expected C2v symmetry [V-O 1.591 (4), V-S 2.387(2)-2.410(2) Å]. The V-O axis is almost parallel to c.
AB - The crystal structure of the title compound, [VO(CS2·NEt2)2], has been determined by direct methods and refined by full-matrix least-squares to R 0.056 for 2 017 reflections. Crystals are monoclinic, space group P21/c, a = 12.863(4), b = 14.023(5), c = 9.558(3) Å, β = 104.05(3)°, Z = 4. The molecular core has the expected C2v symmetry [V-O 1.591 (4), V-S 2.387(2)-2.410(2) Å]. The V-O axis is almost parallel to c.
UR - http://www.scopus.com/inward/record.url?scp=37049097269&partnerID=8YFLogxK
U2 - 10.1039/DT9760000026
DO - 10.1039/DT9760000026
M3 - Article
AN - SCOPUS:37049097269
SN - 1472-7773
SP - 26
EP - 28
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 1
ER -