Crystal structure of bis(diethyldithiocarbamato)oxovanadium(IV)

Kim Henrick, Colin L. Raston, Allan H. White

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)


The crystal structure of the title compound, [VO(CS2·NEt2)2], has been determined by direct methods and refined by full-matrix least-squares to R 0.056 for 2 017 reflections. Crystals are monoclinic, space group P21/c, a = 12.863(4), b = 14.023(5), c = 9.558(3) Å, β = 104.05(3)°, Z = 4. The molecular core has the expected C2v symmetry [V-O 1.591 (4), V-S 2.387(2)-2.410(2) Å]. The V-O axis is almost parallel to c.

Original languageEnglish
Pages (from-to)26-28
Number of pages3
JournalJournal of the Chemical Society, Dalton Transactions
Issue number1
Publication statusPublished - 1976
Externally publishedYes


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