Crystal structure of bis(diethyldithiocarbamato)oxovanadium(IV)

Kim Henrick; Colin L. Raston; Allan H. White

doi:10.1039/DT9760000026

Crystal structure of bis(diethyldithiocarbamato)oxovanadium(IV)

Kim Henrick, Colin L. Raston, Allan H. White

Research output: Contribution to journal › Article › peer-review

28 Citations (Scopus)

Abstract

The crystal structure of the title compound, [VO(CS₂·NEt₂)₂], has been determined by direct methods and refined by full-matrix least-squares to R 0.056 for 2 017 reflections. Crystals are monoclinic, space group P2₁/c, a = 12.863(4), b = 14.023(5), c = 9.558(3) Å, β = 104.05(3)°, Z = 4. The molecular core has the expected C_2v symmetry [V-O 1.591 (4), V-S 2.387(2)-2.410(2) Å]. The V-O axis is almost parallel to c.

Original language	English
Pages (from-to)	26-28
Number of pages	3
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	1
DOIs	https://doi.org/10.1039/DT9760000026
Publication status	Published - 1976
Externally published	Yes

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title = "Crystal structure of bis(diethyldithiocarbamato)oxovanadium(IV)",

abstract = "The crystal structure of the title compound, [VO(CS2·NEt2)2], has been determined by direct methods and refined by full-matrix least-squares to R 0.056 for 2 017 reflections. Crystals are monoclinic, space group P21/c, a = 12.863(4), b = 14.023(5), c = 9.558(3) {\AA}, β = 104.05(3)°, Z = 4. The molecular core has the expected C2v symmetry [V-O 1.591 (4), V-S 2.387(2)-2.410(2) {\AA}]. The V-O axis is almost parallel to c.",

author = "Kim Henrick and Raston, {Colin L.} and White, {Allan H.}",

year = "1976",

doi = "10.1039/DT9760000026",

language = "English",

pages = "26--28",

journal = "Journal of the Chemical Society, Dalton Transactions",

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T1 - Crystal structure of bis(diethyldithiocarbamato)oxovanadium(IV)

AU - Henrick, Kim

AU - Raston, Colin L.

AU - White, Allan H.

PY - 1976

Y1 - 1976

N2 - The crystal structure of the title compound, [VO(CS2·NEt2)2], has been determined by direct methods and refined by full-matrix least-squares to R 0.056 for 2 017 reflections. Crystals are monoclinic, space group P21/c, a = 12.863(4), b = 14.023(5), c = 9.558(3) Å, β = 104.05(3)°, Z = 4. The molecular core has the expected C2v symmetry [V-O 1.591 (4), V-S 2.387(2)-2.410(2) Å]. The V-O axis is almost parallel to c.

AB - The crystal structure of the title compound, [VO(CS2·NEt2)2], has been determined by direct methods and refined by full-matrix least-squares to R 0.056 for 2 017 reflections. Crystals are monoclinic, space group P21/c, a = 12.863(4), b = 14.023(5), c = 9.558(3) Å, β = 104.05(3)°, Z = 4. The molecular core has the expected C2v symmetry [V-O 1.591 (4), V-S 2.387(2)-2.410(2) Å]. The V-O axis is almost parallel to c.

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JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

SN - 1470-479X

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