Crystal structure of bis(hydrazine)bis(hydrazinecarboxylato)cobalt(II)

Edward N. Maslen; Colin L. Raston; Brian W. Skelton; Allan H. White

doi:10.1071/CH9750739

Crystal structure of bis(hydrazine)bis(hydrazinecarboxylato)cobalt(II)

Edward N. Maslen, Colin L. Raston, Brian W. Skelton, Allan H. White

Research output: Contribution to journal › Article › peer-review

19 Citations (Scopus)

Abstract

The crystal structure of the title compound [Co(N₂H₄)₂(NH₂NHCO₂)₂] has been determined at 295 K from X-ray diffractometer data and refined by full-matrix least squares to a residual of 0.059 for the 4985 independent reflections within the limit 2θ < 100° (Mo Kα radiation). Crystal data: monoclinic, P2₁/a, a 9.551(2), b 7.352(2), c 8.110(1) Å, β 122.38(1)°, Z 2. The compound is isostructural with the zinc analogue. The cobalt atom lies on a centre of symmetry; it is six-coordinate, being surrounded by monodentate hydrazine (Co-N, 2.178(2) Å) and bidentate hydrazinecarboxylate ligands (Co-O, 2.064(2) Å; Co-N, 2.198(2) Å).

Original language	English
Pages (from-to)	739-744
Number of pages	6
Journal	Australian Journal of Chemistry
Volume	28
Issue number	4
DOIs	https://doi.org/10.1071/CH9750739
Publication status	Published - 1975
Externally published	Yes

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title = "Crystal structure of bis(hydrazine)bis(hydrazinecarboxylato)cobalt(II)",

abstract = "The crystal structure of the title compound [Co(N2H4)2(NH2NHCO2)2] has been determined at 295 K from X-ray diffractometer data and refined by full-matrix least squares to a residual of 0.059 for the 4985 independent reflections within the limit 2θ < 100° (Mo Kα radiation). Crystal data: monoclinic, P21/a, a 9.551(2), b 7.352(2), c 8.110(1) {\AA}, β 122.38(1)°, Z 2. The compound is isostructural with the zinc analogue. The cobalt atom lies on a centre of symmetry; it is six-coordinate, being surrounded by monodentate hydrazine (Co-N, 2.178(2) {\AA}) and bidentate hydrazinecarboxylate ligands (Co-O, 2.064(2) {\AA}; Co-N, 2.198(2) {\AA}).",

author = "Maslen, {Edward N.} and Raston, {Colin L.} and Skelton, {Brian W.} and White, {Allan H.}",

year = "1975",

doi = "10.1071/CH9750739",

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journal = "Australian Journal of Chemistry",

issn = "0004-9425",

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TY - JOUR

T1 - Crystal structure of bis(hydrazine)bis(hydrazinecarboxylato)cobalt(II)

AU - Maslen, Edward N.

AU - Raston, Colin L.

AU - Skelton, Brian W.

AU - White, Allan H.

PY - 1975

Y1 - 1975

N2 - The crystal structure of the title compound [Co(N2H4)2(NH2NHCO2)2] has been determined at 295 K from X-ray diffractometer data and refined by full-matrix least squares to a residual of 0.059 for the 4985 independent reflections within the limit 2θ < 100° (Mo Kα radiation). Crystal data: monoclinic, P21/a, a 9.551(2), b 7.352(2), c 8.110(1) Å, β 122.38(1)°, Z 2. The compound is isostructural with the zinc analogue. The cobalt atom lies on a centre of symmetry; it is six-coordinate, being surrounded by monodentate hydrazine (Co-N, 2.178(2) Å) and bidentate hydrazinecarboxylate ligands (Co-O, 2.064(2) Å; Co-N, 2.198(2) Å).

AB - The crystal structure of the title compound [Co(N2H4)2(NH2NHCO2)2] has been determined at 295 K from X-ray diffractometer data and refined by full-matrix least squares to a residual of 0.059 for the 4985 independent reflections within the limit 2θ < 100° (Mo Kα radiation). Crystal data: monoclinic, P21/a, a 9.551(2), b 7.352(2), c 8.110(1) Å, β 122.38(1)°, Z 2. The compound is isostructural with the zinc analogue. The cobalt atom lies on a centre of symmetry; it is six-coordinate, being surrounded by monodentate hydrazine (Co-N, 2.178(2) Å) and bidentate hydrazinecarboxylate ligands (Co-O, 2.064(2) Å; Co-N, 2.198(2) Å).

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