Crystal Structure of Bis(N, N-diethyl- dithiocarbamato)(isothiocyanato)iron(III)

Colin L. Raston; William G. Sly; Allan H. White

doi:10.1071/CH9800221

Crystal Structure of Bis(N, N-diethyl- dithiocarbamato)(isothiocyanato)iron(III)

Colin L. Raston, William G. Sly, Allan H. White

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The crystal structure of the title compound [Fe(NCS)(S2CNEt2)2] has been determined by singlecrystal X-ray diffraction methods at 295(1) K and refined to a residual of 0.054 for 998 ‘observed’ reflections. Crystals are orthorhombic, P212121, with a 18.70(2), b 15.43(2), c 6.667(6) Å, Z 4. The iron atom of the complex molecule [Fe(NCS)(S2CNEt2)2] is five-coordinated, being bonded by four sulfur atoms [Fe-S, 2.257-2.300(5) Å] and the nitrogen atom of the thiocyanate [Fe-N, 1.91(2) Å].

Original language	English
Pages (from-to)	221-224
Number of pages	4
Journal	Australian Journal of Chemistry
Volume	33
Issue number	1
DOIs	https://doi.org/10.1071/CH9800221
Publication status	Published - 1980
Externally published	Yes

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title = "Crystal Structure of Bis(N, N-diethyl- dithiocarbamato)(isothiocyanato)iron(III)",

abstract = "The crystal structure of the title compound [Fe(NCS)(S2CNEt2)2] has been determined by singlecrystal X-ray diffraction methods at 295(1) K and refined to a residual of 0.054 for 998 {\textquoteleft}observed{\textquoteright} reflections. Crystals are orthorhombic, P212121, with a 18.70(2), b 15.43(2), c 6.667(6) {\AA}, Z 4. The iron atom of the complex molecule [Fe(NCS)(S2CNEt2)2] is five-coordinated, being bonded by four sulfur atoms [Fe-S, 2.257-2.300(5) {\AA}] and the nitrogen atom of the thiocyanate [Fe-N, 1.91(2) {\AA}].",

author = "Raston, {Colin L.} and Sly, {William G.} and White, {Allan H.}",

year = "1980",

doi = "10.1071/CH9800221",

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journal = "Australian Journal of Chemistry",

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T1 - Crystal Structure of Bis(N, N-diethyl- dithiocarbamato)(isothiocyanato)iron(III)

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AU - Sly, William G.

AU - White, Allan H.

PY - 1980

Y1 - 1980

N2 - The crystal structure of the title compound [Fe(NCS)(S2CNEt2)2] has been determined by singlecrystal X-ray diffraction methods at 295(1) K and refined to a residual of 0.054 for 998 ‘observed’ reflections. Crystals are orthorhombic, P212121, with a 18.70(2), b 15.43(2), c 6.667(6) Å, Z 4. The iron atom of the complex molecule [Fe(NCS)(S2CNEt2)2] is five-coordinated, being bonded by four sulfur atoms [Fe-S, 2.257-2.300(5) Å] and the nitrogen atom of the thiocyanate [Fe-N, 1.91(2) Å].

AB - The crystal structure of the title compound [Fe(NCS)(S2CNEt2)2] has been determined by singlecrystal X-ray diffraction methods at 295(1) K and refined to a residual of 0.054 for 998 ‘observed’ reflections. Crystals are orthorhombic, P212121, with a 18.70(2), b 15.43(2), c 6.667(6) Å, Z 4. The iron atom of the complex molecule [Fe(NCS)(S2CNEt2)2] is five-coordinated, being bonded by four sulfur atoms [Fe-S, 2.257-2.300(5) Å] and the nitrogen atom of the thiocyanate [Fe-N, 1.91(2) Å].

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JF - Australian Journal of Chemistry

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Crystal Structure of Bis(N, N-diethyl- dithiocarbamato)(isothiocyanato)iron(III)

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