TY - JOUR
T1 - Crystal structure of Bis(N, N-diisobutyldithiocarbamato)nickel(II)
AU - Raston, Colin L.
AU - White, Allan H.
PY - 1976
Y1 - 1976
N2 - The crystal structure of the title compound, [Ni(S2CNBu1 2)2], has been determined by X-ray diffraction at 295 K and refined by least squares to a residual of 0.058 for 2031 ‘observed’ reflections. Crystals are monoclinic, P21/a, a = 16.705(6), b = 13.062(5), c = ll.799(5) Å, β = 97.03(3)°, Z = 4. The nickel atom is chelated in an approximately square planar array by two symmetric bidentate dithiocarbarnate ligands, (< Ni-S) 2.201 Å. The ligand symmetry is a good approximation to C2; there is a strong interaction between the tertiary hydrogen atoms and nearby sulphur and nickel atoms.
AB - The crystal structure of the title compound, [Ni(S2CNBu1 2)2], has been determined by X-ray diffraction at 295 K and refined by least squares to a residual of 0.058 for 2031 ‘observed’ reflections. Crystals are monoclinic, P21/a, a = 16.705(6), b = 13.062(5), c = ll.799(5) Å, β = 97.03(3)°, Z = 4. The nickel atom is chelated in an approximately square planar array by two symmetric bidentate dithiocarbarnate ligands, (< Ni-S) 2.201 Å. The ligand symmetry is a good approximation to C2; there is a strong interaction between the tertiary hydrogen atoms and nearby sulphur and nickel atoms.
UR - http://www.scopus.com/inward/record.url?scp=84971050751&partnerID=8YFLogxK
U2 - 10.1071/CH9760523
DO - 10.1071/CH9760523
M3 - Article
AN - SCOPUS:84971050751
SN - 0004-9425
VL - 29
SP - 523
EP - 529
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
IS - 3
ER -