Crystal structure of Bis(N, N-diisobutyldithiocarbamato)nickel(II)

Colin L. Raston, Allan H. White

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The crystal structure of the title compound, [Ni(S2CNBu1 2)2], has been determined by X-ray diffraction at 295 K and refined by least squares to a residual of 0.058 for 2031 ‘observed’ reflections. Crystals are monoclinic, P21/a, a = 16.705(6), b = 13.062(5), c = ll.799(5) Å, β = 97.03(3)°, Z = 4. The nickel atom is chelated in an approximately square planar array by two symmetric bidentate dithiocarbarnate ligands, (< Ni-S) 2.201 Å. The ligand symmetry is a good approximation to C2; there is a strong interaction between the tertiary hydrogen atoms and nearby sulphur and nickel atoms.

Original languageEnglish
Pages (from-to)523-529
Number of pages7
JournalAustralian Journal of Chemistry
Volume29
Issue number3
DOIs
Publication statusPublished - 1976
Externally publishedYes

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