Abstract
The crystal structure of the title compound, [Ni(S2CNBu1 2)2], has been determined by X-ray diffraction at 295 K and refined by least squares to a residual of 0.058 for 2031 ‘observed’ reflections. Crystals are monoclinic, P21/a, a = 16.705(6), b = 13.062(5), c = ll.799(5) Å, β = 97.03(3)°, Z = 4. The nickel atom is chelated in an approximately square planar array by two symmetric bidentate dithiocarbarnate ligands, (< Ni-S) 2.201 Å. The ligand symmetry is a good approximation to C2; there is a strong interaction between the tertiary hydrogen atoms and nearby sulphur and nickel atoms.
| Original language | English |
|---|---|
| Pages (from-to) | 523-529 |
| Number of pages | 7 |
| Journal | Australian Journal of Chemistry |
| Volume | 29 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 1976 |
| Externally published | Yes |
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Raston, C. L., & White, A. H. (1976). Crystal structure of Bis(N, N-diisobutyldithiocarbamato)nickel(II). Australian Journal of Chemistry, 29(3), 523-529. https://doi.org/10.1071/CH9760523