TY - JOUR
T1 - Crystal structure of Bis(O-ethylxanthato)-1, 10-phenanthrolinecadmium(II)
AU - Raston, Colin L.
AU - White, Allan H.
PY - 1976
Y1 - 1976
N2 - The crystal structure of the title compound, [Cd(C12H8N2)(CS2OEt)2], has been determined by X-ray crystallography using diffractometer data at 295 K and refined by full matrix least squares to a residual of 0.06 for 1350 ‘observed’ reflections. Crystals are orthorhombic, P bcn, a = 14.870(4), b = 14.549(8), c = 10.249(1) Å, Z = 4. The molecule lies on a twofold crystallographic axis; the phenanthroline ligand is symmetrically bidentate [Cd-N, 2.386(8) Å], while the ethylxanthateligand is somewhat asymmetric [Cd-S, 2.647(3), 2.727(3)4 with a correspondingly asymmetric C-S geometry [C-S, 1.72(1), 1.66(1) Å].
AB - The crystal structure of the title compound, [Cd(C12H8N2)(CS2OEt)2], has been determined by X-ray crystallography using diffractometer data at 295 K and refined by full matrix least squares to a residual of 0.06 for 1350 ‘observed’ reflections. Crystals are orthorhombic, P bcn, a = 14.870(4), b = 14.549(8), c = 10.249(1) Å, Z = 4. The molecule lies on a twofold crystallographic axis; the phenanthroline ligand is symmetrically bidentate [Cd-N, 2.386(8) Å], while the ethylxanthateligand is somewhat asymmetric [Cd-S, 2.647(3), 2.727(3)4 with a correspondingly asymmetric C-S geometry [C-S, 1.72(1), 1.66(1) Å].
UR - http://www.scopus.com/inward/record.url?scp=84971059685&partnerID=8YFLogxK
U2 - 10.1071/CH9760739
DO - 10.1071/CH9760739
M3 - Article
AN - SCOPUS:84971059685
VL - 29
SP - 739
EP - 742
JO - Australian Journal of Chemistry
JF - Australian Journal of Chemistry
SN - 0004-9425
IS - 4
ER -