Abstract
The crystal structure of the title compound has been determined from single crystal X-ray diffractometer data, and refined by full-matrix least-squares R 0.042 for 1105 observed reflections. Crystals are monoclinic, space group P21/a, a = 18.832(8), b = 7.012(3). c = 8.531(3) Å, β = 96.08(3)°, Z = 4. The structure is comprised of linear chains of cadmium atoms spaced at 3.768(2) and 3.718(2) Å; the cadmium atoms are bridged by one oxygen atom from each ligand [Cd-O 2.288-2.353(4) Å] the remaining two co-ordination sites about the six-co-ordinate cadmium being occupied by the other two non-bridging oxygen atoms [Cd-O 2.221, 2.250(4) Å].
| Original language | English |
|---|---|
| Pages (from-to) | 400-402 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society, Dalton Transactions |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 1975 |
| Externally published | Yes |
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Maslen, E. N., Greaney, T. M., Raston, C. L., & White, A. H. (1975). Crystal structure of catena-di-μ-acetylacetonato-cadmium(II). Journal of the Chemical Society, Dalton Transactions, (5), 400-402. https://doi.org/10.1039/DT9750000400