TY - JOUR
T1 - Crystal structure of catena-di-μ-acetylacetonato-cadmium(II)
AU - Maslen, Edward N.
AU - Greaney, Terence M.
AU - Raston, Colin L.
AU - White, Allan H.
PY - 1975
Y1 - 1975
N2 - The crystal structure of the title compound has been determined from single crystal X-ray diffractometer data, and refined by full-matrix least-squares R 0.042 for 1105 observed reflections. Crystals are monoclinic, space group P21/a, a = 18.832(8), b = 7.012(3). c = 8.531(3) Å, β = 96.08(3)°, Z = 4. The structure is comprised of linear chains of cadmium atoms spaced at 3.768(2) and 3.718(2) Å; the cadmium atoms are bridged by one oxygen atom from each ligand [Cd-O 2.288-2.353(4) Å] the remaining two co-ordination sites about the six-co-ordinate cadmium being occupied by the other two non-bridging oxygen atoms [Cd-O 2.221, 2.250(4) Å].
AB - The crystal structure of the title compound has been determined from single crystal X-ray diffractometer data, and refined by full-matrix least-squares R 0.042 for 1105 observed reflections. Crystals are monoclinic, space group P21/a, a = 18.832(8), b = 7.012(3). c = 8.531(3) Å, β = 96.08(3)°, Z = 4. The structure is comprised of linear chains of cadmium atoms spaced at 3.768(2) and 3.718(2) Å; the cadmium atoms are bridged by one oxygen atom from each ligand [Cd-O 2.288-2.353(4) Å] the remaining two co-ordination sites about the six-co-ordinate cadmium being occupied by the other two non-bridging oxygen atoms [Cd-O 2.221, 2.250(4) Å].
UR - http://www.scopus.com/inward/record.url?scp=37049129041&partnerID=8YFLogxK
U2 - 10.1039/DT9750000400
DO - 10.1039/DT9750000400
M3 - Article
AN - SCOPUS:37049129041
SN - 1472-7773
SP - 400
EP - 402
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 5
ER -