TY - JOUR
T1 - Crystal structure of cis-bis-(N-isopropyldithiocarbamato)nickel(II)
AU - Raston, Colin L.
AU - White, Allan H.
PY - 1974
Y1 - 1974
N2 - The crystal structure of the title compound, has been established by Patterson and Fourier methods from single-crystal photographic X-ray diffraction data, and was refined by full-matrix least-squares to R 0.09 (673 reflections). Crystals are trigonal, space group R3c, a = 22.13(1), c = 15.06(3) Å, Z = 18. The structure is the first example of a square-planar bis(dithiocarbamato) complex with different ligand substituents to adopt the cis-conformation in the solid; this imposes a marked distortion on the NiS4 molecular core and is due to strong hydrogen bonding forces between the -NH- hydrogen and sulphur atoms of adjoining molecules, the overall molecular packing being a cylindrical array down c.
AB - The crystal structure of the title compound, has been established by Patterson and Fourier methods from single-crystal photographic X-ray diffraction data, and was refined by full-matrix least-squares to R 0.09 (673 reflections). Crystals are trigonal, space group R3c, a = 22.13(1), c = 15.06(3) Å, Z = 18. The structure is the first example of a square-planar bis(dithiocarbamato) complex with different ligand substituents to adopt the cis-conformation in the solid; this imposes a marked distortion on the NiS4 molecular core and is due to strong hydrogen bonding forces between the -NH- hydrogen and sulphur atoms of adjoining molecules, the overall molecular packing being a cylindrical array down c.
UR - http://www.scopus.com/inward/record.url?scp=33644760186&partnerID=8YFLogxK
U2 - 10.1039/DT9740001790
DO - 10.1039/DT9740001790
M3 - Article
AN - SCOPUS:33644760186
SN - 1472-7773
SP - 1790
EP - 1792
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 16
ER -